Transition-Metal-Catalyzed Arylation of Unactivated C(sp3)—H Bonds Assisted by Bidentate Directing Groups

doi:10.6023/cjoc201405011

Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (8): 1487-1498.DOI: 10.6023/cjoc201405011 Previous Articles Next Articles

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过渡金属催化的双齿导向基辅助的惰性C（sp³）—H键芳基化

张博, 管晗曦, 刘斌, 史炳锋

浙江大学化学系杭州 310007

收稿日期:2014-05-07 修回日期:2014-05-30 发布日期:2014-06-11
通讯作者: 史炳锋 E-mail:bfshi@zju.edu.cn
基金资助:
国家自然科学基金（No.J1210042）和中央高效基本科研业务费（No.2014QNA3008）资助项目.

Transition-Metal-Catalyzed Arylation of Unactivated C(sp³)—H Bonds Assisted by Bidentate Directing Groups

Zhang Bo, Guan Hanxi, Liu Bin, Shi Bingfeng

Department of Chemistry, Zhejiang university, Hangzhou 310007

Received:2014-05-07 Revised:2014-05-30 Published:2014-06-11
Supported by:
Project supported by the National Natural Science Foundation of China (No. J1210042) and the Fundamental Research Funds for the Central Universities (No. 2014QNA3008).

Recently, transition-metal-catalyzed C—H functionalization has attracted tremendous interest as a valuable tool for carbon-carbon and carbon-heteroatom bond formation. However, due to the inertness of C(sp³)—H bonds and the difficulty to achieving high selectivity among the many chemically similar entities in a given molecule, the selective activation of C(sp³)—H bonds remains a great challenge. The recent progress in transition-metal-catalyzed arylation of unactivated C(sp³)—H bonds assisted by bidentate directing groups is reviewed, including the scope of reactions, mechanism and synthetic applications.

Key words: transition-metal, bidentate directing group, C(sp³)—H activation, arylation

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Zhang Bo, Guan Hanxi, Liu Bin, Shi Bingfeng. Transition-Metal-Catalyzed Arylation of Unactivated C(sp³)—H Bonds Assisted by Bidentate Directing Groups[J]. Chin. J. Org. Chem., 2014, 34(8): 1487-1498.

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过渡金属催化的双齿导向基辅助的惰性C（sp³）—H键芳基化

Transition-Metal-Catalyzed Arylation of Unactivated C(sp³)—H Bonds Assisted by Bidentate Directing Groups

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过渡金属催化的双齿导向基辅助的惰性C（sp3）—H键芳基化