Chinese Journal of Organic Chemistry >
One-Pot Synthesis of A New [2]rotaxane Based on the Phenylene-Diacetylene Crown Ether
Received date: 2014-06-07
Revised date: 2014-07-19
Online published: 2014-08-11
Supported by
Project supported by the National Natural Science Foundation of China (No. 21072066) and the Key Project on the Integration of Industry, Education and Research of Guangdong Province (No. 2012B090700003).
A new [2]rotaxane was synthesized via one-pot method, based on the assembly of the phenylene-diacetylene crown ether (acted as ring molecule) and the paraquat derivative (acted as semi-axle molecule). The HR-MS, 1H NMR and 13C NMR spectra have confirmed that one phenylene-diacetylene crown ether ring threaded though the axle molecule forming the corresponding [2]rotaxane, and the macrocyclic ring moves from one 4,4'-bipyridinium station to another 4,4'-bipyridinium station.
Key words： phenylene-diacetylene crown ether; one-pot method; synthesis; [2]rotaxane
Chen Mujuan , Guo Haoyu , Zhou Songgen , Chen Kun , Jiang Lasheng . One-Pot Synthesis of A New [2]rotaxane Based on the Phenylene-Diacetylene Crown Ether[J]. Chinese Journal of Organic Chemistry, 2014 , 34(12) : 2559 -2565 . DOI: 10.6023/cjoc201406009
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