Chinese Journal of Organic Chemistry >
Synthesis of Magnesium(I) Complexes and Their Applications
Received date: 2015-07-16
Revised date: 2015-09-12
Online published: 2015-09-17
Supported by
Project supported by the National Natural Science Foundation of China (No. 21372117), the Natural Science Foundation of Jiangsu Province (Nos. BK20141468, BK20130952) and the Qing Lan Project of Jiangsu Province.
The valence of the alkaline-earth metals (group 2 metals) usually is 0 and +2. In 2007, the first room temperature stable magnesium(I) complexes were synthesized. Subsequently a series of different organic ligands stablized Mg(I) complexes have been prepared. They can be used as hydrocarbon soluble, stoichiometric, selective, and safe reducing agents in organic and inorganic reactions to replace some traditional reductants. In this review the synthesis of room temperature stable magnesium(I) complexes and their applications in organic and inorganic chemistry are briefly introduced.
Key words： metal-metal bond; univalence; magnesium; synthesis; applications
Ma Mengtao , Wang Weifan , Yao Weiwei . Synthesis of Magnesium(I) Complexes and Their Applications[J]. Chinese Journal of Organic Chemistry, 2016 , 36(1) : 72 -82 . DOI: 10.6023/cjoc201507015
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