Synthesis of Magnesium(I) Complexes and Their Applications

doi:10.6023/cjoc201507015

Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (1): 72-82.DOI: 10.6023/cjoc201507015 Previous Articles Next Articles

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低价(正一价)镁金属化合物的合成及其应用研究进展

马猛涛^a, 王未凡^a, 姚薇薇^b

a 南京林业大学理学院南京 210037
b 南京中医药大学药学院南京 210023

收稿日期:2015-07-16 修回日期:2015-09-12 发布日期:2015-09-17
通讯作者: 马猛涛, 姚薇薇 E-mail:mengtao@njfu.edu.cn;yww0715@hotmail.com
基金资助:
国家自然科学基金(No. 21372117)、江苏省自然科学基金(Nos. BK20141468, BK20130952)和江苏省“青蓝工程”资助项目.

Synthesis of Magnesium(I) Complexes and Their Applications

Ma Mengtao^a, Wang Weifan^a, Yao Weiwei^b

a College of Science, Nanjing Forestry University, Nanjing 210037;
b College of Pharmacy, Nanjing University of Chinese Medicine, Nanjing 210023

Received:2015-07-16 Revised:2015-09-12 Published:2015-09-17
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21372117), the Natural Science Foundation of Jiangsu Province (Nos. BK20141468, BK20130952) and the Qing Lan Project of Jiangsu Province.

The valence of the alkaline-earth metals (group 2 metals) usually is 0 and +2. In 2007, the first room temperature stable magnesium(I) complexes were synthesized. Subsequently a series of different organic ligands stablized Mg(I) complexes have been prepared. They can be used as hydrocarbon soluble, stoichiometric, selective, and safe reducing agents in organic and inorganic reactions to replace some traditional reductants. In this review the synthesis of room temperature stable magnesium(I) complexes and their applications in organic and inorganic chemistry are briefly introduced.

Key words: metal-metal bond, univalence, magnesium, synthesis, applications

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Ma Mengtao, Wang Weifan, Yao Weiwei. Synthesis of Magnesium(I) Complexes and Their Applications[J]. Chin. J. Org. Chem., 2016, 36(1): 72-82.

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低价(正一价)镁金属化合物的合成及其应用研究进展

Synthesis of Magnesium(I) Complexes and Their Applications

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