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Chinese Journal of Organic Chemistry >

2016 , Vol. 36 >Issue 5: 889 - 912

DOI: https://doi.org/10.6023/cjoc201511017

REVIEW

Progress in Diazo Compounds Mediated Transition-Metal-Catalyzed C—H Alkylation

  • Wang Liang ,
  • Li Zhana ,
  • Wan Kang ,
  • Qu Xinga ,
  • Hu Siqian ,
  • Wang Feng
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  • a. Key Laboratory of Optoelectronic Chemical Materials and Devices of Ministry of Education, School of Chemical and Environmental Engineering, Jianghan University, Wuhan 430056;
    b. College of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000

Received date: 2015-11-06

  Revised date: 2016-01-10

  Online published: 2016-02-01

Supported by

Project supported by the National Natural Science Foundation of China (No. 21302064) and the Scientific Research Project of Hubei Provincial Department of Education (No. B2015231).

Fold

Abstract

Diazo compounds had been widely employed as a class of environment friendly and highly efficient coupling reagents in transition-metal-catalyzed C—H bonds insertion reactions. Recently, C—H alkylation of various arenes and heteroarenes has been achieved enormous successes using diazo compounds as the alkylation reagents under a new catalytic model. The recent progress in diazo compounds mediated transition-metal-catalyzed C—H alkylation and tandem C—H alkylation/cyclization is reviewed, including reaction mechanism and synthetic applications. Furthermore, the prospects of this reaction are also discussed.

Key words： diazo compounds; transition-metal-catalysis; C—H activation; alkyaltion

Cite this article

Wang Liang , Li Zhana , Wan Kang , Qu Xinga , Hu Siqian , Wang Feng . Progress in Diazo Compounds Mediated Transition-Metal-Catalyzed C—H Alkylation[J]. Chinese Journal of Organic Chemistry, 2016 , 36(5) : 889 -912 . DOI: 10.6023/cjoc201511017

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