Chinese Journal of Organic Chemistry >
Preparation and Catalytic Properties of a Novel Bamboo Fiber Supported-Palladium Catalyst (Fiber-Pd)
Received date: 2015-10-29
Revised date: 2016-01-30
Online published: 2016-02-18
Supported by
Project supported by the Sichuan Province Education Office Fostering Projects (No. 15CZ0026), the Youth Found of Sichuan Province Education Office (Nos. 12ZB074, 13ZB0002, 11ZB024), and the Startup Foundation of Ph. D. Scientific Research of Neijiang Normal University (No. 2012B05).
A novel bamboo fiber supported palladium (Fiber-Pd) catalyst was prepared with diphenylphosphinite fiber and palladium dichloride in ethanol. The as-prepared Fiber-Pd catalyst was characterized by X-ray photoelectron spectrometer (XPS), X-ray diffraction (XRD), thermogravimetric analyses (TGA), inductively coupled plasma-atomic emission spectrometry (ICP-AES), and transmission electron microscopy (TEM). The catalyst was applied to the Suzuki cross-coupling reaction between sodium tetraarylborate and aryl halides. Excellent yields of the corresponding functionalized biaryls were obtained when the reaction was performed in the presence of NaHCO3 as base in PEG 400/H2O at 85 ℃ within a short reaction time. It is noteworthy that the present protocol is highly efficient as 4 equiv. aryl halides reacted with 1 equiv. sodium tetraarylborate cleanly to provide high yield of the cross-coupling products in short reaction time. The catalyst can be easily separated and recovered from the reaction mixture by filtration and reused. This process has significant features of short reaction time, broad substrate scopes, easy isolation of the product, and atom-efficient coupling under mild conditions in environmentally friendly media in air.
Zhou Wenjun , Wang Dan , Zhang Xiazhong , Zeng Bin . Preparation and Catalytic Properties of a Novel Bamboo Fiber Supported-Palladium Catalyst (Fiber-Pd)[J]. Chinese Journal of Organic Chemistry, 2016 , 36(6) : 1412 -1418 . DOI: 10.6023/cjoc201510037
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