Preparation and Catalytic Properties of a Novel Bamboo Fiber Supported-Palladium Catalyst (Fiber-Pd)

doi:10.6023/cjoc201510037

Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (6): 1412-1418.DOI: 10.6023/cjoc201510037 Previous Articles Next Articles

Notes

一种新型竹纤维负载钯催化剂的制备及催化性能

周文俊^a,b, 王丹^a, 张霞忠^a,b, 曾彬^a

a 内江师范学院化学化工学院内江 641112;
b 四川省高等学校果类废弃物资源化重点实验室内江 641112

收稿日期:2015-10-29 修回日期:2016-01-30 发布日期:2016-02-18
通讯作者: 张霞忠 E-mail:chemzhwj@126.com
基金资助:
四川省教育厅成果转化培育(No.15CZ0026)、四川省青年基金(Nos.12ZB074,13ZB0002,11ZB024)和内江师范学院博士科研启动费(No.2012B05)资助项目.

Preparation and Catalytic Properties of a Novel Bamboo Fiber Supported-Palladium Catalyst (Fiber-Pd)

Zhou Wenjun^a,b, Wang Dan^a, Zhang Xiazhong^a,b, Zeng Bin^a

aCollege of Chemistry and Chemical Engineering, Neijiang Normal University, Neijiang 641112;
b Key Laboratory of Fruit Waste Treatment and Resource Recycling of the Sichuan Provincial College, Sichuan 641112

Received:2015-10-29 Revised:2016-01-30 Published:2016-02-18
Supported by:
Project supported by the Sichuan Province Education Office Fostering Projects (No. 15CZ0026), the Youth Found of Sichuan Province Education Office (Nos. 12ZB074, 13ZB0002, 11ZB024), and the Startup Foundation of Ph. D. Scientific Research of Neijiang Normal University (No. 2012B05).

1. Preparation and Catalytic Properties of a Novel Bamboo Fiber Supported-Palladium Catalyst (Fiber-Pd).PDF(448KB)

Abstract

A novel bamboo fiber supported palladium (Fiber-Pd) catalyst was prepared with diphenylphosphinite fiber and palladium dichloride in ethanol. The as-prepared Fiber-Pd catalyst was characterized by X-ray photoelectron spectrometer (XPS), X-ray diffraction (XRD), thermogravimetric analyses (TGA), inductively coupled plasma-atomic emission spectrometry (ICP-AES), and transmission electron microscopy (TEM). The catalyst was applied to the Suzuki cross-coupling reaction between sodium tetraarylborate and aryl halides. Excellent yields of the corresponding functionalized biaryls were obtained when the reaction was performed in the presence of NaHCO₃ as base in PEG 400/H₂O at 85 ℃ within a short reaction time. It is noteworthy that the present protocol is highly efficient as 4 equiv. aryl halides reacted with 1 equiv. sodium tetraarylborate cleanly to provide high yield of the cross-coupling products in short reaction time. The catalyst can be easily separated and recovered from the reaction mixture by filtration and reused. This process has significant features of short reaction time, broad substrate scopes, easy isolation of the product, and atom-efficient coupling under mild conditions in environmentally friendly media in air.

Key words: bamboo fiber supported palladium, preparation, Suzuki reaction, sodium tetraphenylborate, aryl halide

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Zhou Wenjun, Wang Dan, Zhang Xiazhong, Zeng Bin. Preparation and Catalytic Properties of a Novel Bamboo Fiber Supported-Palladium Catalyst (Fiber-Pd)[J]. Chin. J. Org. Chem., 2016, 36(6): 1412-1418.

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一种新型竹纤维负载钯催化剂的制备及催化性能

Preparation and Catalytic Properties of a Novel Bamboo Fiber Supported-Palladium Catalyst (Fiber-Pd)

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