Chinese Journal of Organic Chemistry >
Further Chemical Constituents from the Rare Chloranthaceae Plant Chloranthus sessilifolius
Received date: 2016-02-01
Revised date: 2016-03-04
Online published: 2016-03-28
Supported by
Project supported by National Natural Science Foundation of China (Nos. 21472021, 81273401, 21575029) and the National Basic Research Program of China (973 Program, No. 2013CB530700).
Two diterpenoids and a few miscellaneous components (one phenethylpropanoid, one flavonoid, and one lignan) were isolated from the MeOH extract of the whole plant of the rare Chloranthaceae plant Chloranthus sessilifolius during a further phytochemical reinvestigation. Based on their spectroscopic data (i.e., IR, UV, 1D/2D NMR, ECD, and HR-ESIMS) and/or comparing with those reported physicochemical data in related literature, the structures were determined to be (3R,5S,6S,9S,10S,13S)-3,6,13-trihydroxy-ent-abieta-8(14)-en-7-one (1), 3α,15-dihydroxy-13α-methoxy-ent-abieta-8(14)-en- 7-one (2), p-coumaroyl-β-phenethyl amine (3), narigenin trimethyl ether (4), and (3R,4R,3'R,4'R)-6,6'-dimethoxy-3,4,3',4'- tetrahydro-2H,2H'-[3,3']-bichromenyl-4,4'-diol (5). Among them, compound 1 is new, while compounds 3~5 were isolated from the Chloranthus genus for the first time.
Wang Lijun , Lau Choiwan , Xiong Juan , Hu Jinfeng . Further Chemical Constituents from the Rare Chloranthaceae Plant Chloranthus sessilifolius[J]. Chinese Journal of Organic Chemistry, 2016 , 36(7) : 1677 -1680 . DOI: 10.6023/cjoc201602002
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