Chinese Journal of Organic Chemistry >
Carrier-Free and Recyclable PdCl2-Catalyzed Suzuki-Miyaura and Mizoroki-Heck Reactions in Water/Ionic Liquid Media
Received date: 2017-06-14
Revised date: 2017-07-11
Online published: 2017-08-09
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21563015, 51363009) and the Natural Science Foundation of Jiangxi Province (No. 20151BAB203010).
Efficient and unsupported protocols were developed for PdCl2-catalyzed Suzuki-Miyaura and Mizoroki-Heck reactions using water/ionic liquid systems to afford the cross-coupling products with excellent yields. It is noteworthy that the PdCl2/K2CO3/water/ionic liquid systems can be recovered and used for 3~5 cycles directly. The results suggest that the unsupported and recyclable systems can be extended to the other realm of C-C bond formation.
Key words： carrier-free; recyclability; water/ionic liquid; coupling reaction
Tang Boxiao , Fang Xiaoniu , Kuang Renyun , Cai Jinhua , Wu Jianhong . Carrier-Free and Recyclable PdCl2-Catalyzed Suzuki-Miyaura and Mizoroki-Heck Reactions in Water/Ionic Liquid Media[J]. Chinese Journal of Organic Chemistry, 2017 , 37(11) : 2956 -2961 . DOI: 10.6023/cjoc201706016
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