Carrier-Free and Recyclable PdCl2-Catalyzed Suzuki-Miyaura and Mizoroki-Heck Reactions in Water/Ionic Liquid Media

doi:10.6023/cjoc201706016

Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (11): 2956-2961.DOI: 10.6023/cjoc201706016 Previous Articles Next Articles

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水/离子液体中无负载PdCl₂循环催化Suzuki-Miyaura和Mizoroki-Heck反应的研究

唐伯孝, 方小牛, 匡仁云, 蔡金华, 吴建宏

井冈山大学化学化工学院应用化学研究所江西省配位化学重点实验室吉安 343009

收稿日期:2017-06-14 修回日期:2017-07-11 发布日期:2017-08-09
通讯作者: 唐伯孝 E-mail:520tangboxiao@163.com
基金资助:
国家自然科学基金（Nos.21563015，51363009）和江西省自然科学基金（No.20151BAB203010）资助项目.

Carrier-Free and Recyclable PdCl₂-Catalyzed Suzuki-Miyaura and Mizoroki-Heck Reactions in Water/Ionic Liquid Media

Tang Boxiao, Fang Xiaoniu, Kuang Renyun, Cai Jinhua, Wu Jianhong

Key Laboratory of Coordination Chemistry of Jiangxi Province, Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jinggangshan University, Ji'an 343009

Received:2017-06-14 Revised:2017-07-11 Published:2017-08-09
Contact: 10.6023/cjoc201706016 E-mail:520tangboxiao@163.com
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21563015, 51363009) and the Natural Science Foundation of Jiangxi Province (No. 20151BAB203010).

1. Carrier-Free and Recyclable PdCl₂-Catalyzed Suzuki-Miyaura and Mizoroki-Heck Reactions in Water/Ionic Liquid Media.PDF(988KB)

Abstract

Efficient and unsupported protocols were developed for PdCl₂-catalyzed Suzuki-Miyaura and Mizoroki-Heck reactions using water/ionic liquid systems to afford the cross-coupling products with excellent yields. It is noteworthy that the PdCl₂/K₂CO₃/water/ionic liquid systems can be recovered and used for 3~5 cycles directly. The results suggest that the unsupported and recyclable systems can be extended to the other realm of C-C bond formation.

Key words: carrier-free, recyclability, water/ionic liquid, coupling reaction

Cite this article

Tang Boxiao, Fang Xiaoniu, Kuang Renyun, Cai Jinhua, Wu Jianhong. Carrier-Free and Recyclable PdCl₂-Catalyzed Suzuki-Miyaura and Mizoroki-Heck Reactions in Water/Ionic Liquid Media[J]. Chin. J. Org. Chem., 2017, 37(11): 2956-2961.

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水/离子液体中无负载PdCl₂循环催化Suzuki-Miyaura和Mizoroki-Heck反应的研究

Carrier-Free and Recyclable PdCl₂-Catalyzed Suzuki-Miyaura and Mizoroki-Heck Reactions in Water/Ionic Liquid Media

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水/离子液体中无负载PdCl2循环催化Suzuki-Miyaura和Mizoroki-Heck反应的研究