Chinese Journal of Organic Chemistry >
Research Progress for the Thiolysis Reaction of Halobenzonitrile
Received date: 2017-07-03
Revised date: 2017-09-23
Online published: 2017-10-20
Supported by
Project supported by the National Natural Science Foundation of China (No. 21362019), the Natural Science Foundation of Inner Mongolia (No. 2016MS0207) and the "Light of West China" Program of Chinese Academy of Sciences.
Halobenzonitrile is an important raw material in the fields of medicine, pesticide and materials. Halobenzonitrile has a nitrile group and a halo group which all could react with nucleophile reagents. The law for the selective synthesis of halothiobenzamide or mercaptobenzonitrile from the reaction of halobenzonitrile and different sulfur source is summarized. It is found that the halothiobenzamide product could be synthesized under protonic acid condition from halobenzonitrile, while the mercaptobenzonitrile product would be formed under the alkaline conditions.
Li Shanshan , Hong Hailong , Han Limin , Zhang Tianmiao , Wang Yunlong , Zhu Ning . Research Progress for the Thiolysis Reaction of Halobenzonitrile[J]. Chinese Journal of Organic Chemistry, 2018 , 38(2) : 304 -315 . DOI: 10.6023/cjoc201707002
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