Research Progress for the Thiolysis Reaction of Halobenzonitrile

doi:10.6023/cjoc201707002

Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (2): 304-315.DOI: 10.6023/cjoc201707002 Previous Articles Next Articles

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卤代苯腈硫解反应规律的研究进展

李闪闪, 洪海龙, 韩利民, 张田苗, 王云龙, 竺宁

内蒙古工业大学化工学院呼和浩特 010051

收稿日期:2017-07-03 修回日期:2017-09-23 发布日期:2017-10-20
通讯作者: 洪海龙, 竺宁 E-mail:honghailong_1979@163.com;zhuning2622@yahoo.com
基金资助:
国家自然科学基金（No.21362019）、内蒙自然科学基金（No.2016MS0207）和中国科学院“西部之光”人才培养计划项目.

Research Progress for the Thiolysis Reaction of Halobenzonitrile

Li Shanshan, Hong Hailong, Han Limin, Zhang Tianmiao, Wang Yunlong, Zhu Ning

Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010051

Received:2017-07-03 Revised:2017-09-23 Published:2017-10-20
Contact: 10.6023/cjoc201707002 E-mail:honghailong_1979@163.com;zhuning2622@yahoo.com
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21362019), the Natural Science Foundation of Inner Mongolia (No. 2016MS0207) and the "Light of West China" Program of Chinese Academy of Sciences.

Halobenzonitrile is an important raw material in the fields of medicine, pesticide and materials. Halobenzonitrile has a nitrile group and a halo group which all could react with nucleophile reagents. The law for the selective synthesis of halothiobenzamide or mercaptobenzonitrile from the reaction of halobenzonitrile and different sulfur source is summarized. It is found that the halothiobenzamide product could be synthesized under protonic acid condition from halobenzonitrile, while the mercaptobenzonitrile product would be formed under the alkaline conditions.

Key words: chalcogens, heteroatom compounds, synthetic methods, halobenzonitrile, halothiobenzamide, mercaptobenzonitrile

Cite this article

Li Shanshan, Hong Hailong, Han Limin, Zhang Tianmiao, Wang Yunlong, Zhu Ning. Research Progress for the Thiolysis Reaction of Halobenzonitrile[J]. Chin. J. Org. Chem., 2018, 38(2): 304-315.

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卤代苯腈硫解反应规律的研究进展

Research Progress for the Thiolysis Reaction of Halobenzonitrile

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