Chinese Journal of Organic Chemistry >
Recent Advances in the Synthesis of Heterocyclic Compounds via Pd-Catalyzed C(sp3)-H Bond Activation
Received date: 2018-05-13
Revised date: 2018-06-26
Online published: 2018-07-24
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21372231, 21673260).
Heterocyclic compounds are not only important intermediates in organic synthesis and medicine synthesis, but also the basic building framework of biologically active natural products. In recent years, Pd-catalyzed C(sp3)-H bonds activation has been demonstrated as one of the hot topics in the field of heterocyclic compound synthesis because of its high atomic economic characteristics. Herein, the recent research progress in the construction of heterocyclic compounds via Pd-catalyzed C(sp3)-H bond activation is summarized according to the classification of the ring number of heterocyclic compounds (mainly including N, O heterocycles). The reaction selectivity, substrate compatibility, reaction mechanism, advantages and disadvantages as well as an outlook in this field are also discussed.
Key words： Pd-catalyzed; C (sp3)-H bond activation; heterocyclic compounds
Zhao Kang , Yang Lei , Liu Jianhua , Xia Chungu . Recent Advances in the Synthesis of Heterocyclic Compounds via Pd-Catalyzed C(sp3)-H Bond Activation[J]. Chinese Journal of Organic Chemistry, 2018 , 38(11) : 2833 -2857 . DOI: 10.6023/cjoc201805028
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