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Chinese Journal of Organic Chemistry >

2020 , Vol. 40 >Issue 7: 2062 - 2070

DOI: https://doi.org/10.6023/cjoc202003008

Study on Reaction of γ-Valerolactone and Amine Catalyzed by Zirconium-Based Lewis Acids

  • Kong Qingshan ,
  • Li Xinglong ,
  • Xu Huajian ,
  • Fu Yao
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  • a School of Food and Biological Engineering, University of Science and Technology of China, Hefei 230601;
    b Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials, Chinese Academy of Sciences Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, Department of Chemistry, University of Science and Technology of China, Hefei 230026

Received date: 2020-03-08

  Revised date: 2020-04-02

  Online published: 2020-04-17

Supported by

Project supported by the National Key Research and Development Program of China (No. 2018YFB1501604), the National Natural Science Foundation of China (No. 21472033), the Key Research and Development Program Projects in Anhui Province (No. 201904a07020069), and the Fundamental Research Funds for the Central Universities.

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Abstract

γ-Valerolactone (GVL) is an important biomass platform molecule, it can be converted into high value-added chemicals and fuel, which has important application prospects. This article describes a method for the synthesis of hydroxyamides and pyrrolidones from GVL and amine compounds by reductive amination/cyclization reactions under mild conditions using zirconium-based Lewis acid catalysts Zr-P-O and ZrOCl2·8H2O, respectively. In particular, a moderately high product yield can be obtained with the absence of a solvent. This method further lays the foundation for the application research of GVL.

Key words： γ-valerolactone; hydroxyamide; pyrrolidone; Lewis acid catalysis; zirconium-based catalyst

Cite this article

Kong Qingshan , Li Xinglong , Xu Huajian , Fu Yao . Study on Reaction of γ-Valerolactone and Amine Catalyzed by Zirconium-Based Lewis Acids[J]. Chinese Journal of Organic Chemistry, 2020 , 40(7) : 2062 -2070 . DOI: 10.6023/cjoc202003008

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