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Chinese Journal of Organic Chemistry >

2020 , Vol. 40 >Issue 7: 1860 - 1873

DOI: https://doi.org/10.6023/cjoc202002038

Recent Advances in Transition-Metal Catalyzed Defunctionalization Reaction

  • Dong Xiaojuan ,
  • Jin Weiwei ,
  • Liu Chenjiang
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  • School of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046

Received date: 2020-02-26

  Revised date: 2020-04-10

  Online published: 2020-04-23

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21702175, 21961037) and the 1000 Youth Talents Plan.

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Abstract

Functional groups are atoms or groups that determine the chemical properties of organic compounds. It often plays the role of guiding group in organic synthesis chemistry. Defunctionalization is the chemical transformation of a substrate with more functional groups into a compound with fewer functional groups, which has positive applications in solving environmental problems, resource shortage and biomass degradation. But due to the bond energy, heating, acid or base are often involved in defunctionalization. In recent years, defunctionalization has been moving toward a greener and more sustainable direction. Metal catalysis provides a new way for defunctionalization. The recent applications of different metal-mediated defunctionalization in organic synthesis and their mechanism are summarized.

Key words： transition metal; defunctionalization; protonation; selectivity

Cite this article

Dong Xiaojuan , Jin Weiwei , Liu Chenjiang . Recent Advances in Transition-Metal Catalyzed Defunctionalization Reaction[J]. Chinese Journal of Organic Chemistry, 2020 , 40(7) : 1860 -1873 . DOI: 10.6023/cjoc202002038

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