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Chinese Journal of Organic Chemistry >

2020 , Vol. 40 >Issue 10: 3262 - 3278

DOI: https://doi.org/10.6023/cjoc202005008

Progress in Iridium-Catalyzed Asymmetric Allylic Substitution Reactions via Synergetic Catalysis

  • Tian Fei ,
  • Zhang Jian ,
  • Yang Wulin ,
  • Deng Weiping
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  • School of Pharmacy and Shanghai Key Laboratory of New Drug Design, East China University of Science and Technology, Shanghai 200237

Received date: 2020-05-04

  Revised date: 2020-05-23

  Online published: 2020-06-01

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21772038, 21901072), the Fundamental Research Funds for the Central Universities (No. 222201814048) and the Shanghai Sailing Program (No. 18YF140560).

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Abstract

Iridium-catalyzed asymmetric allylic substitution reaction has become one of the most important methods for the synthesis of chiral compounds due to its exceptional branched regioselectivity and excellent enantioselectivity. The scope of nucleophiles will be further expanded by synergetic catalysis system of iridium and other catalysts (organocatalysts, other transition metal catalysts). Besides, it is possible to improve the enantioselectivity of the reaction and even realize the stereodivergent synthesis of the products with multiple stereocenters. The progress in the field of catalytic asymmetric allylic substitutions through synergetic iridium and organocatalysis or other transition metal catalysis is summarized. These reactions are classified according to the types of catalysts (aminocatalyst, phase transfer catalyst, Brønsted acid, Lewis base, transition metal). Meanwhile, the mechanism of representative reactions, the existing problems and the prospects in this area are briefly described.

Key words： asymmetric catalysis; allylic substitution reaction; iridium catalyst; synergetic catalysis

Cite this article

Tian Fei , Zhang Jian , Yang Wulin , Deng Weiping . Progress in Iridium-Catalyzed Asymmetric Allylic Substitution Reactions via Synergetic Catalysis[J]. Chinese Journal of Organic Chemistry, 2020 , 40(10) : 3262 -3278 . DOI: 10.6023/cjoc202005008

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