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Chinese Journal of Organic Chemistry >

2020 , Vol. 40 >Issue 9: 2755 - 2763

DOI: https://doi.org/10.6023/cjoc202003068

Phathalocyanine Metal Complexes (M=Fe, Co, and Cu) Catalyzed Aerobic Oxidation of 2-Amino-benzyl Alcohols to Access Quinazolines and Quinolines

  • Liu Zilin ,
  • Zhang Xiaojie ,
  • Zhang Heng ,
  • Jiang Hui ,
  • Zhao Xuemei ,
  • Shi Linlin ,
  • Zhu Xinju ,
  • Hao Xinqi ,
  • Song Maoping
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  • College of Chemistry, Zhengzhou University, Zhengzhou 450001

Received date: 2020-03-31

  Revised date: 2020-05-27

  Online published: 2020-06-13

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21672192, 21803059, U1904212, 21929101).

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Abstract

Phathalocyanine metal complexes catalyzed oxidative condensation of 2-aminobenzyl alcohols with nitriles and ketones has been developed under air to afford quinazolines and quinolines, respectively. After systematic investigation, iron(II) phathalocyanine displayed higher catalytic activity in quinazoline synthesis and copper(II) phathalocyanine showed higher efficiency in quinoline preparation. Under the optimized conditions, various nitriles and ketones were well adaptted to give the corresponding products in good yields.

Key words： phathalocyanine metal complexes; quinazolines; quinolines; aerobic oxidation

Cite this article

Liu Zilin , Zhang Xiaojie , Zhang Heng , Jiang Hui , Zhao Xuemei , Shi Linlin , Zhu Xinju , Hao Xinqi , Song Maoping . Phathalocyanine Metal Complexes (M=Fe, Co, and Cu) Catalyzed Aerobic Oxidation of 2-Amino-benzyl Alcohols to Access Quinazolines and Quinolines[J]. Chinese Journal of Organic Chemistry, 2020 , 40(9) : 2755 -2763 . DOI: 10.6023/cjoc202003068

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