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Chinese Journal of Organic Chemistry >

2020 , Vol. 40 >Issue 9: 2669 - 2677

DOI: https://doi.org/10.6023/cjoc202005013

Efficient Activation of Allylic Alcohols in Pd-Catalyzed Allylic Substitution Reactions

  • Ma Xiantao ,
  • Yu Jing ,
  • Wang Zilong ,
  • Zhang Yun ,
  • Zhou Qiuju
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  • Green Catalysis & Synthesis Key Laboratory of Xinyang City, College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang, Henan 464000

Received date: 2020-05-06

  Revised date: 2020-05-24

  Online published: 2020-06-13

Supported by

Project supported by the Key Scientific and Technological Project of Henan Province (No. 192102310031), the Key Scientific Research Project of Universities of Henan Province (No. 19B150018), the Nanhu Scholars Program for Young Scholars of Xinyang Normal University and the Young Core Instructor Program of Xinyang Normal University (No. 2018GGJS-05).

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Abstract

Owing to the poor leaving character of hydroxy group, the efficient activation of allylic alcohols is important to allylic substitution reaction. In recent years, the efficient activation of allylic alcohols by non-typical acid activators and even no extra activators has been rapidly developed, and provides a novel approach to efficient activation of allylic alcohols. The recent developments in this area are summarized on the basis of different activation modes and mechanisms.

Key words： allylic alcohols; allylic substitution; Pd catalysis; activation by acid or acidic hydrogen; hydrogen bond activation

Cite this article

Ma Xiantao , Yu Jing , Wang Zilong , Zhang Yun , Zhou Qiuju . Efficient Activation of Allylic Alcohols in Pd-Catalyzed Allylic Substitution Reactions[J]. Chinese Journal of Organic Chemistry, 2020 , 40(9) : 2669 -2677 . DOI: 10.6023/cjoc202005013

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