Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (9): 2669-2677.DOI: 10.6023/cjoc202005013 Previous Articles     Next Articles


马献涛, 于静, 王子龙, 张赟, 周秋菊   

  1. 信阳师范学院化学化工学院 信阳市绿色催化和合成重点实验室 河南信阳 464000
  • 收稿日期:2020-05-06 修回日期:2020-05-24 发布日期:2020-06-13
  • 通讯作者: 马献涛
  • 基金资助:

Efficient Activation of Allylic Alcohols in Pd-Catalyzed Allylic Substitution Reactions

Ma Xiantao, Yu Jing, Wang Zilong, Zhang Yun, Zhou Qiuju   

  1. Green Catalysis & Synthesis Key Laboratory of Xinyang City, College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang, Henan 464000
  • Received:2020-05-06 Revised:2020-05-24 Published:2020-06-13
  • Supported by:
    Project supported by the Key Scientific and Technological Project of Henan Province (No. 192102310031), the Key Scientific Research Project of Universities of Henan Province (No. 19B150018), the Nanhu Scholars Program for Young Scholars of Xinyang Normal University and the Young Core Instructor Program of Xinyang Normal University (No. 2018GGJS-05).

Owing to the poor leaving character of hydroxy group, the efficient activation of allylic alcohols is important to allylic substitution reaction. In recent years, the efficient activation of allylic alcohols by non-typical acid activators and even no extra activators has been rapidly developed, and provides a novel approach to efficient activation of allylic alcohols. The recent developments in this area are summarized on the basis of different activation modes and mechanisms.

Key words: allylic alcohols, allylic substitution, Pd catalysis, activation by acid or acidic hydrogen, hydrogen bond activation