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Chinese Journal of Organic Chemistry >

2020 , Vol. 40 >Issue 10: 3154 - 3165

DOI: https://doi.org/10.6023/cjoc202005043

Recent Progress of Chiral Iminophosphorane Catalysis

  • Zhang Yanxia ,
  • Han Jianwei
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  • a Shanghai Key Laboratory of Functional Materials Chemistry, Department of Fine Chemicals, School of Chemistry & Molecular Engineering, East China University of Science and Technology, Shanghai 200237;
    b Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Received date: 2020-05-18

  Revised date: 2020-06-19

  Online published: 2020-07-01

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21472213, 21202186) and the Croucher Foundation of Hong Kong.

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Abstract

As organocatalysts, organic base catalysts play an important role in the quest for optically pure compounds. Chiral iminophosphoranes, being organosuperbases, are very stable under air and moisture conditions, thereby providing an attractive platform for the design of various asymmetric organocatalysts. The recent achievements concerning chiral iminophosphoranes in the development of both organocatalysis and their applications in asymmetric synthesis are summarized and discussed.

Key words： chiral iminophosphorane; asymmetric catalysis; research progress; organocatalysis

Cite this article

Zhang Yanxia , Han Jianwei . Recent Progress of Chiral Iminophosphorane Catalysis[J]. Chinese Journal of Organic Chemistry, 2020 , 40(10) : 3154 -3165 . DOI: 10.6023/cjoc202005043

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