Recent Progress of Chiral Iminophosphorane Catalysis

doi:10.6023/cjoc202005043

Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (10): 3154-3165.DOI: 10.6023/cjoc202005043 Previous Articles Next Articles

Special Issue: 黄乃正院士七十华诞专辑

手性膦腈碱有机催化的研究进展

张艳霞^a,b, 韩建伟^a,b

a 华东理工大学化学与分子工程学院精细化工系上海市功能性材料化学重点实验室上海 200237;
b 中国科学院上海有机化学研究所沪港化学合成联合实验室上海 200032

收稿日期:2020-05-18 修回日期:2020-06-19 发布日期:2020-07-01
通讯作者: 韩建伟 E-mail:jianweihan@ecust.edu.cn
基金资助:
国家自然科学基金（Nos.21472213，21202186）和香港裘槎基金资助项目.

Recent Progress of Chiral Iminophosphorane Catalysis

Zhang Yanxia^a,b, Han Jianwei^a,b

a Shanghai Key Laboratory of Functional Materials Chemistry, Department of Fine Chemicals, School of Chemistry & Molecular Engineering, East China University of Science and Technology, Shanghai 200237;
b Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Received:2020-05-18 Revised:2020-06-19 Published:2020-07-01
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21472213, 21202186) and the Croucher Foundation of Hong Kong.

As organocatalysts, organic base catalysts play an important role in the quest for optically pure compounds. Chiral iminophosphoranes, being organosuperbases, are very stable under air and moisture conditions, thereby providing an attractive platform for the design of various asymmetric organocatalysts. The recent achievements concerning chiral iminophosphoranes in the development of both organocatalysis and their applications in asymmetric synthesis are summarized and discussed.

Key words: chiral iminophosphorane, asymmetric catalysis, research progress, organocatalysis

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Zhang Yanxia, Han Jianwei. Recent Progress of Chiral Iminophosphorane Catalysis[J]. Chinese Journal of Organic Chemistry, 2020, 40(10): 3154-3165.

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手性膦腈碱有机催化的研究进展

Recent Progress of Chiral Iminophosphorane Catalysis

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