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Chinese Journal of Organic Chemistry >

2020 , Vol. 40 >Issue 11: 3686 - 3696

DOI: https://doi.org/10.6023/cjoc202006008

Recent Progress in C(sp3)-H Asymmetric Oxidation Catalyzed by Bioinspired Metal Complexes

  • Sun Qiangsheng ,
  • Sun Wei
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  • State Key Laboratory for Oxo Synthesis and Selective Oxidation, Center for Excellence in Molecular Synthesis, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000

Received date: 2020-06-05

  Revised date: 2020-06-19

  Online published: 2020-07-09

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21773273, 21473226, 21902166), the Key Research Program of Frontier Sciences, CAS (No. QYZDJ-SSW-SLH051) and the Natural Science Foundation of Jiangsu Province (No. BK20170420).

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Abstract

C—H oxidation represents one of the most important reactions in organic chemistry. In particular, asymmetric C—H oxidation, which can directly convert simple alkanes into chiral alcohols, ketones, aldehydes and so on, provides more economic and efficient access to the synthesis of complex molecules. Although increasing efforts have been devoted to this area, asymmetric C—H oxidation is still far away from the goal due to the inert nature of C—H and the subtle stereo-difference of C—H bonds. The factors that dictate the selectivity of asymmetric C—H oxidation, mechanism of the C—H oxidation catalyzed by enzyme and some successful examples achieved by biomimetic metal complexes bearing various ligands are reviewed.

Key words： C-H oxidation; metal complex; asymmetric oxidation

Cite this article

Sun Qiangsheng , Sun Wei . Recent Progress in C(sp3)-H Asymmetric Oxidation Catalyzed by Bioinspired Metal Complexes[J]. Chinese Journal of Organic Chemistry, 2020 , 40(11) : 3686 -3696 . DOI: 10.6023/cjoc202006008

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