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Chinese Journal of Organic Chemistry >

2020 , Vol. 40 >Issue 11: 3672 - 3685

DOI: https://doi.org/10.6023/cjoc202006076

Artificial Stimuli-Responsive Catalytic Systems for Switchable Asymmetric Catalysis

  • Tang Yuping ,
  • He Yanmei ,
  • Fan Qinghua
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  • a Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences(CAS), Beijing 100190;
    b School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049

Received date: 2020-06-30

  Revised date: 2020-08-03

  Online published: 2020-08-11

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21772204, 21521002), and the Key Research Program of Frontier Sciences, Chinese Academy of Sciences (No. QYZDJ-SSW-SLH023).

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Abstract

Inspired by enzyme allosteric catalysis, the study on artificial stimuli-responsive asymmetric catalytic systems has attracted more and more attentions in recent years. In order to precisely control the catalytic activity and stereoselectivity, stimuli-responsive functionalities have been introduced into the catalyst design. A variety of asymmetric reactions featuring on/off-switchable catalysis and/or stereodivergent catalysis have been successfully achieved by using light-, coordination-, pH-and redox-driven chiral switchable catalysts. By selecting representative examples, the catalyst design principles, allosteric mechanism and their applications in switchable asymmetric reactions sre mainly introduced. At the same time, advantages and limitations of this emerging field are summarized, and perspectives for its future development are given.

Key words： asymmetric catalysis; stimuli-responsiveness; chiral switchable catalyst; allosteric catalysis; enantiodivergent catalysis

Cite this article

Tang Yuping , He Yanmei , Fan Qinghua . Artificial Stimuli-Responsive Catalytic Systems for Switchable Asymmetric Catalysis[J]. Chinese Journal of Organic Chemistry, 2020 , 40(11) : 3672 -3685 . DOI: 10.6023/cjoc202006076

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