Chinese Journal of Organic Chemistry >
Synthesis and Application of a Novel Fluorescent Probe for Sequential Recognition Cu2+ and Glyphosate
Received date: 2021-09-29
Revised date: 2021-10-28
Online published: 2021-11-25
Supported by
National Natural Science Foundation of China(21908034); Natural Science Foundation of Heilongjiang Province(LH2021H001)
A novel fluorescent probe L based on coumarin-derived acylhydrazone was designed and synthesized by using 7-(4-methoxyphenyl)ethynyl coumarin as report group. The probe L showed high selectivity and good anti-interference ability towards Cu2+ ion through the color of solution changed from light brown to yellow for naked-eye detection and significant fluorescence intensity quenched in the dimethyl sulfoxide (DMSO)/H2O [V:V=7:3, 2-[4-(2-hydroxyethyl)piperazin-1- yl]ethanesulfonic acid (HEPES) 10 mmol/L, pH=7.4] solution, and the detection limit of probe L to Cu2+ could reach 5.6×10–8 mol/L. Meanwhile, the L-Cu2+ system has high selectivity, good sensitivity, wide pH range (5~9) and low detection limit (11.3 ng/mL) for the detection of glyphosate by ligand replacement method. In addition, glyphosate detection was assessed within the actual water samples for testing the L-Cu2+actual application and the method was expected to the detection in environmental samples.
Mianyuan Wu , Yanchao Yu , Yang Liu , Jun You , Wenju Wu , Bo Liu . Synthesis and Application of a Novel Fluorescent Probe for Sequential Recognition Cu2+ and Glyphosate[J]. Chinese Journal of Organic Chemistry, 2022 , 42(3) : 803 -811 . DOI: 10.6023/cjoc202109049
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