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Chinese Journal of Organic Chemistry >

2022 , Vol. 42 >Issue 2: 631 - 640

DOI: https://doi.org/10.6023/cjoc202108050

ARTICLES

CuI-Catalyzed Regioselective Synthesis of 3-Arylcoumarins with Arylamines under Mild Conditions

  • Yamin Sun ,
  • Xiyong Li ,
  • Jinwei Yuan ,
  • Jialin Yu ,
  • Shuainan Liu
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  • a Department of Pharmaceuticals and Medical Devices, Weihai Ocean Vocational College, Weihai, Shandong 264300
    b School of Chemistry & Chemical Engineering, Henan University of Technology, Zhengzhou 450001
* Corresponding author. E-mail:

Received date: 2021-08-26

  Revised date: 2021-09-26

  Online published: 2022-02-24

Supported by

Natural Science Foundation of Henan Provincial Department of Education(21A150016); Training Program of Youth Backbone Teacher of Henan Province(2018GGJS178); Innovative Funds Plan of Henan University of Technology(2020ZKCJ29)

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Abstract

A mild and convenient method has been developed for the construction of 3-arylcoumarins through CuI-catalyzed reaction of coumarins with arylamines under mild conditions. The present protocol simply utilizes readily available starting materials as substrates, inexpensive metal as catalyst, providing various 3-arylcoumarins with good functional groups toleration in moderate to good yields. Moreover, control experiments show that the reaction proceeds by a radical pathway.

Key words： coumarin; arylamine; copper-catalyzed; arylation; radical reaction

Cite this article

Yamin Sun , Xiyong Li , Jinwei Yuan , Jialin Yu , Shuainan Liu . CuI-Catalyzed Regioselective Synthesis of 3-Arylcoumarins with Arylamines under Mild Conditions[J]. Chinese Journal of Organic Chemistry, 2022 , 42(2) : 631 -640 . DOI: 10.6023/cjoc202108050

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