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Chinese Journal of Organic Chemistry >

2022 , Vol. 42 >Issue 6: 1849 - 1855

DOI: https://doi.org/10.6023/cjoc202201023

NOTES

Magnetic Se/Fe/PCN-Catalyzed Oxidative Cracking Alkenes in O2

  • Wenjian Zhou ,
  • Xinrui Xiao ,
  • Yonghong Liu ,
  • Xu Zhang
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  • a School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002
    b Guangling College, Yangzhou University, Yangzhou, Jiangsu 225000
*E-mail: ;

Received date: 2022-01-17

  Revised date: 2022-02-23

  Online published: 2022-03-08

Supported by

Jiangsu Provincial Six Talent Peaks Project(XCL-090); Nature Science Foundation of Jiangsu Province(BK20181449); Priority Academic Program Development of Jiangsu Higher Education Institutions

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Abstract

Oxidative cracking reaction of alkenes is applied not only in the synthesis of carbonyl compounds, but also in biomass conversion and degradation of organic pollutants. It is an organic chemical reaction with potential industrial application value. Developing a suitable catalyst to promote the reaction using molecular oxygen as a cheap and safe oxidant under mild conditions is a meaningful research topic in the interdisciplinary field of organic chemistry and material chemistry. In this work, Se/Fe/PCN catalyst was designed and prepared. The experimental results showed that the material was of excellent catalytic activity for the oxidative cracking of styrene derivatives. Notably, the selectivity of the reaction is good, and the selectivity of aldehydes in the product could reach 70%~90%. The catalyst was magnetically separable, and could be reused for the next turn of reaction.

Key words： selenium; iron; oxidative cracking; alkene; carbonyl

Cite this article

Wenjian Zhou , Xinrui Xiao , Yonghong Liu , Xu Zhang . Magnetic Se/Fe/PCN-Catalyzed Oxidative Cracking Alkenes in O2[J]. Chinese Journal of Organic Chemistry, 2022 , 42(6) : 1849 -1855 . DOI: 10.6023/cjoc202201023

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