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Chinese Journal of Organic Chemistry >

2022 , Vol. 42 >Issue 8: 2568 - 2573

DOI: https://doi.org/10.6023/cjoc202202008

ARTICLES

Hydrocarboxylation of Alkenes with Formate Salts via Photocatalysis

  • Yan Huang ,
  • Qian Zhang ,
  • Lewu Zhan ,
  • Jing Hou ,
  • Bindong Li
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  • College of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094
† These authors contributed equally to this work.
* E-mail: ;

Received date: 2022-02-08

  Revised date: 2022-04-11

  Online published: 2022-04-22

Supported by

National Natural Science Foundation of China(21901118); Natural Science Foundation of Jiangsu Province(BK20190430); Fundamental Research Funds for the Central Universities(30921011206)

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Abstract

A transition-metal-free β-selective hydrocarboxylation of alkenes under mild conditions has been developed using a formate salt as the reductant, carbonyl source. A broad range of alkenes were compatible with this method and can be efficiently converted into value-added carboxylic acid products. This method also features low catalyst loading, good functional group tolerance, and easy scalability.

Key words： alkenes; hydrocarboxylation; photocatalysis; carbon dioxide radical anion; formate salt

Cite this article

Yan Huang , Qian Zhang , Lewu Zhan , Jing Hou , Bindong Li . Hydrocarboxylation of Alkenes with Formate Salts via Photocatalysis[J]. Chinese Journal of Organic Chemistry, 2022 , 42(8) : 2568 -2573 . DOI: 10.6023/cjoc202202008

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