Chinese Journal of Organic Chemistry >
A Novle Quinoline Hydrazone-Based Fluorescent Probe for Sequential Determination of Cu2+/Glyphosate and Its Applications
Received date: 2022-03-02
Revised date: 2022-03-28
Online published: 2022-04-22
Supported by
National Natural Science Foundation of China(21908034); Natural Science Foundation of Heilongjiang Province(LH2021H001)
A novel quinoline hydrazone-based fluorescent probe L was designed and synthesized using quinoline-2-carboxylic acid and 7-(diethylamino)coumarin-3-carbaldehyde as raw materials. The spectral properties of probe L were studied by UV-Vis/fluorescence spectrophotometry. The results showed that probe L had obvious ON-OFF fluorescence response to Cu2+ in the tetrahydrofuran (THF)/H2O [V:V=3:7, 2-[4-(2-hydroxyethyl)piperazin-1-yl]ethanesulfonic acid (HEPES) 10 mmol/ L, pH=7.4] solution, and it displayed efficiency, high specificity and sensitivity. Job’s plot and high resolution mass spectrometry showed that the stoichiometry of L-Cu2+ complex was estimated to be 1:1. Meanwhile, complex L-Cu2+ showed high selectivity and good anti-interference ability towards glyphosate through the significant fluorescence enhancement, and the detection limit of complex L-Cu2+ to glyphosate could reach 5.6×10–8 mol/L (9.5×10–3 mg/L). In addition, complex L- Cu2+ was able to sense glyphosate by “naked-eye” according to the color change, and applied to glyphosate detection in the actual water samples.
Key words： quinoline hydrazone; fluorescent probe; Cu2+; glyphosate; sequential recognition
Mianyuan Wu , Jun You , Yanchao Yu , Wenju Wu . A Novle Quinoline Hydrazone-Based Fluorescent Probe for Sequential Determination of Cu2+/Glyphosate and Its Applications[J]. Chinese Journal of Organic Chemistry, 2022 , 42(8) : 2559 -2567 . DOI: 10.6023/cjoc202203009
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