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Chinese Journal of Organic Chemistry >

2022 , Vol. 42 >Issue 7: 1950 - 1959

DOI: https://doi.org/10.6023/cjoc202203029

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Cyclization and Coupling Reactions Promoted by Potassium tert-Butoxide

  • Lizhi Zhang ,
  • Yongjian Liao ,
  • Ning Chen ,
  • Lei Huang ,
  • Min Zhou
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  • School of Ethnic Medicine, Yunnan Minzu University, Kunming 650031
†These authors contribute equally to this work
* E-mail:

Received date: 2022-03-15

  Revised date: 2022-04-19

  Online published: 2022-04-29

Supported by

National Natural Science Foundation of China(32060101); Yunnan Applied Basic Research Projects for Excellent Young Scholars(202001AW070002); Yunnan Ten Thousand Talents Program(YNWR-QNBJ-2019-206); Candidates of the Young and Middle Aged Academic Leaders of Yunnan Province(2019HB016)

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Abstract

Over the past few decades, transition metal-catalyzed reactions have been developed into a powerful tool for building various chemical bonds. At the same time, non-metal-promoted chemical bond construction reactions have attracted more and more attention of synthetic chemists because of the avoiding of using expensive metal catalysts and ligands, resulting in the reduce of reaction costs and environmental pollution. It conforms to the concept of green chemistry development. Among them, potassium tert-butoxide-promoted cyclization and coupling reactions have been rapidly developed. The intramolecular cyclization and intermolecular coupling reactions involving potassium tert-butoxide since 2000 are summarized, and the possible reaction mechanisms are elucidated, which can help chemists better understand the development of this field and promote the development of this field.

Key words： potassium t-butoxide; intramolecular cyclization; free radical reaction; coupling reaction

Cite this article

Lizhi Zhang , Yongjian Liao , Ning Chen , Lei Huang , Min Zhou . Cyclization and Coupling Reactions Promoted by Potassium tert-Butoxide[J]. Chinese Journal of Organic Chemistry, 2022 , 42(7) : 1950 -1959 . DOI: 10.6023/cjoc202203029

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