Chinese Journal of Organic Chemistry >
Recent Advances in C—X Bond Metathesis Reactions
Received date: 2022-02-05
Revised date: 2022-04-20
Online published: 2022-05-07
Supported by
National Natural Science Foundation of China(21925111); National Natural Science Foundation of China(21790333); China Postdoctoral Science Foundation(2021M703070); Strategic Priority Research Program of the Chinese Academy of Sciences(XDPB14)
Metathesis reaction, as a new type of chemical bond reorganization reaction, proved remarkably powerful for constructing inaccessible complex molecules by other methods in both industrial and academic settings, which greatly promotes the development of synthetic chemistry. However, most of the known metathesis reactions are mainly limited to the recombination reaction of multiple bonds, and the metathesis reactions of C—X single bonds are still in their infancy and face many opportunities and challenges. This is mainly due to the high bond energy of the C—X bonds, which is hard to break and reorganize. The progress of C—Si, C—P, C—S, C—I, C—O and C—N bonds metathesis reactions and their applications in organic synthesis are summarized according to the type of bonding.
Bangkui Yu , Hanmin Huang . Recent Advances in C—X Bond Metathesis Reactions[J]. Chinese Journal of Organic Chemistry, 2022 , 42(8) : 2376 -2389 . DOI: 10.6023/cjoc202202003
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