Chinese Journal of Organic Chemistry >
BF3•Et2O Promoted Dienone-Phenol Type Rearrangement to Synthesize Phosphepine with Aggregation Induced Luminescence (AIE) Effect
Received date: 2022-04-06
Revised date: 2022-05-01
Online published: 2022-05-18
Supported by
National Natural Science Foundation of China(22171245); National Natural Science Foundation of China(22101262); National Natural Science Foundation of China(21672193); Key Scientific and Technological Project of Henan Province(202102310327); Zhengzhou University
Very recently, phosphepines has emerged as a new luminogen. Further explorations of this new motif in optical materials have been hampered by the lack of general and practical methods for their synthesis and derivation. The rearrangement of dienones promoted by acid or base is widely used in the preparation of phenols. A series of phosphepines with aggregation induced luminescence (AIE) effect were synthesized by the dienone-phenol rearrangement reaction of spirodienone six-membered phosphacycles in the presence of BF3•Et2O.
Ze Guo , Di Wu , Lili Wang , Zheng Duan . BF3•Et2O Promoted Dienone-Phenol Type Rearrangement to Synthesize Phosphepine with Aggregation Induced Luminescence (AIE) Effect[J]. Chinese Journal of Organic Chemistry, 2022 , 42(8) : 2481 -2487 . DOI: 10.6023/cjoc202204012
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