Chinese Journal of Organic Chemistry >
Tris(4-ethynylphenyl)amine-Based Conjugated Microporous Polymers and Its Photocatalytic Water Splitting Hydrogen Evolution
Received date: 2022-03-29
Revised date: 2022-05-10
Online published: 2022-06-17
Supported by
National Natural Science Foundation of China(21805248); National Natural Science Foundation of China(U2004196); Natural Science Foundation of Henan Province(162300410318); Open Project of Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences(K2016-8); Doctor Research Project of Zhengzhou University of Light Industry(2013BSJJ017)
Conjugated microporous polymers (CMPs) have shown attractive application prospects in the field of photocatalytic water splitting hydrogen evolution because of their excellent stability and adjustable properties. To develop novel multi-functional building blocks for CMPs photocatalysts and explore effective methods to tune their properties, based on tris- (4-ethynylphenyl) amine (TEA) unit and benzothiadiazole (BT) unit with different linking positions, four CMPs FS1, FS2, FS3 and FS4 have been synthesized with Sonogashira-Hagihara coupling reaction. The linking positions of BT units in them are 5,6, 4,5, 4,6 and 4,7, respectively. It suggests that the four polymers all have stable photocatalytic hydrogen evolution performance under visible light driving. FS4 with 4,7-linked polymer has the best performance, and its hydrogen evolution efficiency is as high as 115.74×10–3 μmol•mg–1•h–1, nearly three times than that of FS1. It shows that TEA is an excellent multi-functional building block of CMPs photocatalyst, and the linking position regulation of BT unit is an effective means to tune the performance of TEA based CMPs.
Junping Du , Shanshan Feng , Jie Zhang , Yonghui Zhang , Shiwen Wang , Lifeng Han , Junli Chen . Tris(4-ethynylphenyl)amine-Based Conjugated Microporous Polymers and Its Photocatalytic Water Splitting Hydrogen Evolution[J]. Chinese Journal of Organic Chemistry, 2022 , 42(9) : 2967 -2974 . DOI: 10.6023/cjoc202203056
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