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Chinese Journal of Organic Chemistry >

2022 , Vol. 42 >Issue 10: 3302 - 3321

DOI: https://doi.org/10.6023/cjoc202205046

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Recent Advances in Ni-Catalyzed Asymmetric Reductive Difunctionalization of Alkenes

  • Yuanyuan Ping ,
  • Haixia Song ,
  • Wangqing Kong
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  • a The Institute for Advanced Studies, Wuhan University, Wuhan 430072
    b Hunan Petrochemical Vocational Technology College, Yueyang, Hunan 414012
* Corresponding authors. E-mail: ;
E-mail:

Received date: 2022-05-24

  Revised date: 2022-06-27

  Online published: 2022-07-05

Supported by

National Natural Science Foundation of China(22171215); Fundamental Research Funds for the Central Universities(2042021kf0032); China Postdoctoral Science Foundation(2020M680108); Postdoctoral Foundation of Hubei Province(211000012)

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Abstract

Alkenes are cheap and easily available bulk industrial feedstocks. Difunctionalization of alkenes can rapidly construct complex molecules, which have broad applications in organic synthesis. Compared with traditional redox-neutral alkene difunctionalization, the reductive difunctionalization of alkenes can introduce two different electrophiles to both sides of the carbon-carbon double bond, which has the advantages of mild reaction conditions, high functional group tolerance, and no need for pre-prepared organometallic reagents. The latest research progress in nickel-catalyzed reductive difunctionalization of alkenes is summarized. The development prospect of the reaction is prospected.

Key words： nickel catalysis; alkenes; difunctionalization reaction; reductive cross-coupling; enantioselectivity

Cite this article

Yuanyuan Ping , Haixia Song , Wangqing Kong . Recent Advances in Ni-Catalyzed Asymmetric Reductive Difunctionalization of Alkenes[J]. Chinese Journal of Organic Chemistry, 2022 , 42(10) : 3302 -3321 . DOI: 10.6023/cjoc202205046

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