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Chinese Journal of Organic Chemistry >

2022 , Vol. 42 >Issue 11: 3890 - 3895

DOI: https://doi.org/10.6023/cjoc202205005

NOTES

Selective Epoxidation of β-Ionone Catalyzed by Iron-Doped Se/C

  • Hong'en Cao ,
  • Peizi Li ,
  • Xiaobi Jing ,
  • Hongwei Zhou
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  • aSchool of Horticulture and Plant Protection, Yangzhou University, Yangzhou, Jiangsu 225009
    bKey Laboratory of Green Pesticide and Agriculture Bioengineering of Ministry of Education, Guizhou University, Guiyang 550025
    cCollege of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001
    dSchool of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002
*E-mail: ;

Received date: 2022-05-04

  Revised date: 2022-06-26

  Online published: 2022-07-14

Supported by

Natural Science Foundation of Zhejiang Province(LY19B020004); Open Fund of the State Key Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering/Key Laboratory of Ministry of Education(2020GDGP0101); Open Project of Jiaxing Key Laboratory for Creation of Animal Models & Synthesis of Lead Compounds of New Drug(jxsz21006); Priority Academic Program Development of Jiangsu Higher Education Institutions

Fold

Abstract

As an important intermediate in pharmaceutical synthesis, 5,6-epoxy-β-ionone has unique industrial application value. Recently, an iron-doped Se/C catalyst has been designed and prepared by calcining a mixture of methylselenized glucose with FeCl3. The material could activate the molecular oxygen to achieve the selective epoxidation of β-ionone affording 5,6-epoxy-β-ionone. The catalyst is stable and recyclable, and the catalytic reaction process did not require any additive, so that the production cost could be obviously reduced. This cheap and safe catalytic oxidation technology using molecular oxygen as oxidant is of good industrial application values.

Key words： 5,6-epoxy-β-ionone; β-ionone; selenium; molecular oxygen; green catalysis

Cite this article

Hong'en Cao , Peizi Li , Xiaobi Jing , Hongwei Zhou . Selective Epoxidation of β-Ionone Catalyzed by Iron-Doped Se/C[J]. Chinese Journal of Organic Chemistry, 2022 , 42(11) : 3890 -3895 . DOI: 10.6023/cjoc202205005

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