Chinese Journal of Organic Chemistry >
Recent Progress on the Electrochemical Difunctionalization of Alkenes/Alkynes
Received date: 2022-04-27
Revised date: 2022-06-13
Online published: 2022-09-09
Supported by
National Natural Science Foundation of China(21961042); Basic Ability Improvement Project of Young and Middle-Aged Teachers in Guangxi Colleges(2021KY0587); Basic Ability Improvement Project of Young and Middle-Aged Teachers in Guangxi Colleges(2022KY0572); Program of Yulin Normal University(G2021ZK16); Program of Yulin Normal University(G2022ZK08)
The difunctionalization of unsaturated hydrocarbons (alkenes or alkynes) is an important strategy to introduce functional groups, and is also an important method to synthesize polysubstituted hydrocarbons, which is widely used in the fields of total synthesis of natural products and drug synthesis. The latest research progress on the electrochemically enabled difunctionalization of alkenes or alkynes in recent five years is summarized. According to the classification of difunctionalization of alkenes and cyclization of unsaturated hydrocarbon, the application and the related reaction mechanism are introduced. It is hoped that this review can be referred to the future application in organic synthesis of electrochemic- mediated difunctionalization of alkenes/alkynes.
Key words： electrochemistry; alkenes/alkynes; difunctionalization
Xiuying Li , Pingfang Tao , Yongyu Cheng , Qiong Hu , Weijuan Huang , Yun Li , Zhihui Luo , Guobao Huang . Recent Progress on the Electrochemical Difunctionalization of Alkenes/Alkynes[J]. Chinese Journal of Organic Chemistry, 2022 , 42(12) : 4169 -4201 . DOI: 10.6023/cjoc202204066
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