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Chinese Journal of Organic Chemistry >

2023 , Vol. 43 >Issue 5: 1751 - 1760

DOI: https://doi.org/10.6023/cjoc202212022

REVIEWS

Zirconium and Titanium Mediated Hydroboration of Alkenes and Alkynes

  • Sida Li ,
  • Xing-Zhong Shu ,
  • Lipeng Wu
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  • a State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000
    b State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000
    c University of Chinese Academy of Sciences, Beijing 100049
* Corresponding authors. E-mail: ;

Received date: 2022-12-16

  Revised date: 2023-01-09

  Online published: 2023-01-18

Supported by

National Natural Science Foundation of China(22271295); Cooperation Foundation of Lanzhou Institute of Chemical Physics for Young Scholars(HZJJ21-01)

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Abstract

The transition metal-catalyzed hydroboration of alkenes and alkynes is one of the most efficient way for the production of boronate esters. This type of reaction is 100% atom economic, the starting material is readily available, and the products are diverse. It is noticed that most of the known catalytic systems are based on late-transition-metals such as Rh, Ir, Pd, Pt, Co, Fe and Cu. The use of early-transition-metals of zirconium and titanium, on the other hand, is very scarce. In this short review, the development of application in zirconium and titanium mediated hydroboration of alkene and alkyne is summarized, and the research trends of this area are also discussed.

Key words： zirconium; titanium; alkenes; alkynes; hydroboration

Cite this article

Sida Li , Xing-Zhong Shu , Lipeng Wu . Zirconium and Titanium Mediated Hydroboration of Alkenes and Alkynes[J]. Chinese Journal of Organic Chemistry, 2023 , 43(5) : 1751 -1760 . DOI: 10.6023/cjoc202212022

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