Chinese Journal of Organic Chemistry >
Palladium-Catalyzed Asymmetric Hydrofunctionalizations of Conjugated Dienes
Received date: 2023-02-11
Revised date: 2023-03-18
Online published: 2023-04-10
Supported by
The National Natural Science Foundation of China(22071262); The Science and Technology Commission of Shanghai Municipality(22ZR1475200); The Shanghai Rising-Star Program(20QA1411300)
Because of the broad substrate availability, high atom economy and efficient stereocontrol, palladium-catalzyed asymmetric hydrofunctionalizations of conjugated dienes have emerged as an efficient route to construct enantioenriched allylic motifs, including allylic C—C, C—N, C—S, C—P, C—Si and C—O bonds. The development, advance and mechanistic features of this area in the past decades are summarized. Based on the types of allylic stereogenic centers constructed via this strategy, the review is divided into six parts, including asymmetric hydroalkylation, hydroamination, hydrophosphinylation, hydrosulfonylation, hydrosilylation and hydroalkoxylation.
Yuchao Wang , Jinbiao Liu , Zhitao He . Palladium-Catalyzed Asymmetric Hydrofunctionalizations of Conjugated Dienes[J]. Chinese Journal of Organic Chemistry, 2023 , 43(8) : 2614 -2627 . DOI: 10.6023/cjoc202302010
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