Chinese Journal of Organic Chemistry >
Progress in the Study of Dehydroxymethylation of Primary Alcohol
Received date: 2023-03-04
Revised date: 2023-04-04
Online published: 2023-04-14
Supported by
The National Natural Science Foundation of China(22071185); The National Natural Science Foundation of China(22271224); The Fundamental Research Funds for the Central Universities(2042019kf0008); The Wuhan University Startup Funding
Primary alcohols are abundant and readily available, which have been widely used as feedstock chemicals for the synthesis of agrochemicals, food additives, fragrances, pharmaceuticals and so on. The dehydroxymethylation reaction is an effective strategy to prepare hydrocarbons with one less carbon atom from primary alcohols, which has attracted tremendous attentions of many organic chemists and applied in biomass degradation and drug synthesis. The development of dehydroxy- methylation of primary alcohol on the base of the reaction characters is reviewed, including transition-metal catalyzed dehydroxymethylation to access methane and water, transition-metal catalyzed dehydroxymethylation to produce carbon monoxide and hydrogen, transition-metal catalyzed dehydroxymethylation to generate formaldehyde, as well as transition-metal free dehydroxymethylation to furnish formic acid and water. Each type of reaction is systematically summarized according to the catalytic system, the substrates scope and reaction mechanism.
Xinqiang Chen , Jing Zhang . Progress in the Study of Dehydroxymethylation of Primary Alcohol[J]. Chinese Journal of Organic Chemistry, 2023 , 43(8) : 2711 -2719 . DOI: 10.6023/cjoc202303009
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