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Chinese Journal of Organic Chemistry >

2023 , Vol. 43 >Issue 9: 3312 - 3318

DOI: https://doi.org/10.6023/cjoc202301024

An Efficient and Rapid Synthesis of α-Aminonitriles via Strecker Reaction Catalyzed by Humic Acid

  • Min Xi ,
  • Chao Duan ,
  • Jie Chi ,
  • Tian Fu ,
  • Xiaolong Su ,
  • Hongshe Wang
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  • Shaanxi Key Laboratory for Phytochemistry, Department of Chemistry and Chemical Engineering, Baoji University of Arts and Sciences, Baoji, Shaanxi 721013
* E-mail:

Received date: 2023-01-29

  Revised date: 2023-03-26

  Online published: 2023-05-11

Supported by

National Natural Science Foundation of China(51902004); Natural Science Foundation of Shaanxi Province(2020KW-041)

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Abstract

An efficient one pot three-component Strecker reaction for the green synthesis of α-aminonitriles from carbonyl compounds, amines and trimethylsilyl cyanide (TMSCN) in the presence of a catalytic amount of humic acid catalyst under solvent-free conditions at room temperature has been developed. This methodology has advantages of high yield, no need for metal catalysts, short reaction time, mild reaction conditions, simple operation, green and reusable catalyst.

Key words： Strecker reaction; humic acid; carbonyl compound; amine; α-aminonitrile

Cite this article

Min Xi , Chao Duan , Jie Chi , Tian Fu , Xiaolong Su , Hongshe Wang . An Efficient and Rapid Synthesis of α-Aminonitriles via Strecker Reaction Catalyzed by Humic Acid[J]. Chinese Journal of Organic Chemistry, 2023 , 43(9) : 3312 -3318 . DOI: 10.6023/cjoc202301024

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