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Chinese Journal of Organic Chemistry >

2023 , Vol. 43 >Issue 9: 3055 - 3066

DOI: https://doi.org/10.6023/cjoc202303036

Recent Progress in Light-Driven Direct Dehydroxylation and Derivation of Alcohols

  • Boyu Yan ,
  • Jieliang Wu ,
  • Jinfei Deng ,
  • Dan Chen ,
  • Xiushen Ye ,
  • Qiuli Yao
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  • a College of Pharmacy, Zunyi Medical University, Zunyi, Guizhou 563000
    b Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xi'ning 810008
* E-mail:

Received date: 2023-03-23

  Revised date: 2023-05-04

  Online published: 2023-06-07

Supported by

National Natural Science Foundation of China(22161053); National Natural Science Foundation of China(21801261); Guizhou Science and Technology Department([2020]1Z003); Guizhou Education Department(20195201900); Zunyi Medical University Outstanding Young Talents(18zy-003); Thousand Talents Plan of Qinghai Province

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Abstract

Conventional methods for the reduction of alcohols mainly deal with the indirect cleavages of Csp3—O bond involving tedious activated steps. In contrast, the more straightforward direct reduction of naturally abundant aliphatic alcohols to alkanes or other reductive derivatives poses a challenge to organic chemists due to the inherently stable and less reactive Csp3—O bond. The development of direct reductive strategies induced by light is of utmost importance due to their atom economy, step economy and redox economy, and many progresses have been made in this area these years. However, very few reviews on this topic has been reported so far. Herein, the recent progress in the light-driven direct deoxygenation of alcohols with emphasis on important advances last ten years is reviewed, which is expected to further promote the vigorous development of this field.

Key words： alcohols; reduction; alkylation; dehydroxylation; photochemistry

Cite this article

Boyu Yan , Jieliang Wu , Jinfei Deng , Dan Chen , Xiushen Ye , Qiuli Yao . Recent Progress in Light-Driven Direct Dehydroxylation and Derivation of Alcohols[J]. Chinese Journal of Organic Chemistry, 2023 , 43(9) : 3055 -3066 . DOI: 10.6023/cjoc202303036

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