Chinese Journal of Organic Chemistry >
Recent Advances in Functionalization of Aromatic C(sp2)—H Bonds Based on N-Nitroso Direction
Received date: 2023-05-24
Revised date: 2023-07-11
Online published: 2023-08-15
Supported by
Natural Science Foundation of Zhejiang Province(LZ22B020003); National Natural Science Foundation of China(22071171)
In recent years, examples of activation of aromatic C(sp2)—H bonds successfully constructing C—C bonds and C—heteroatom bonds through N-nitroso synergistic chelation with transition metals have been reported. It is based on the oxidative cleavage of internal N—N bonds, and does not require the addition of external oxidants during the reaction process. After the reaction completion, it can leave on its own, which has made it develop into a new and efficient directing group, and has received widespread attention from researchers. The latest research progress on functionalization of aromatic C(sp2)—H bonds based on N-nitroso direction is summarized.
Fang Wang , Lei Wang . Recent Advances in Functionalization of Aromatic C(sp2)—H Bonds Based on N-Nitroso Direction[J]. Chinese Journal of Organic Chemistry, 2023 , 43(12) : 4157 -4167 . DOI: 10.6023/cjoc202305029
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