Chinese Journal of Organic Chemistry >
Recent Advances in Electrochemical Silylation
Received date: 2023-08-24
Revised date: 2023-09-27
Online published: 2023-10-30
Supported by
National Natural Science Foundation of China(22122102); National Natural Science Foundation of China(22101113); National Natural Science Foundation of China(22271134); Guangdong Provincial Key Laboratory of Catalysis(2020B121201002); Guangdong Pearl River Talent Program(2019QN01Y628); Shenzhen Science and Technology Innovation Committee(RCJC20221008092723013)
Organosilicon compounds are widely applied in synthesis, materials, medicine and other fields due to their unique physical and chemical properties, and have attracted widespread attention from chemists. Therefore, it is particularly important to develop mild and efficient synthesis methods to construct organosilicon compounds. In recent years, the rapid development of electrochemistry provided a new strategy for the synthesis of organosilicon compounds. Due to its advantages of green and mild conditions, simple and efficient reactions, and no need for additional redox reagents, significant progress has been made in the synthesis of organosilicon compounds through electrochemical silylation reactions. The latest progress in electro- chemical silylation is mainly reviewed from two aspects: electrochemical silylation reactions via cathodic reduction, and electrochemical silylation reactions via anodic oxidation.
Key words： electrochemistry; silylation; organosilicon; cathodic reduction; anodic oxidation
Junyong Wang , Na Li , Jie Ke , Chuan He . Recent Advances in Electrochemical Silylation[J]. Chinese Journal of Organic Chemistry, 2024 , 44(3) : 927 -939 . DOI: 10.6023/cjoc202308022
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