Chinese Journal of Organic Chemistry >
Recent Progress on Methods for the Preparation of Mono/Di/Trifluoromethoxylation Reagents
Received date: 2024-04-30
Revised date: 2024-05-23
Online published: 2024-06-13
Supported by
2023 Youth Research and Innovation Talent Training Program of Harbin University of Commerce; University Discipline Collaborative Innovation Achievements Construction Project(LJGXCG2022-086); Scientific Research Project on Traditional Chinese Medicine in Heilongjiang Province(ZYW2023-075)
Fluorine-containing organic molecules have broad applications in the fields of pharmaceuticals, agrochemicals, and material science. In the pharmaceutical industry, the incorporation of fluorine-containing methoxy groups can enhance the bioavailability and metabolic stability of drugs, while also modulating the stereochemistry and electronic structure of the molecules, thereby improving drug efficacy and selectivity. In the agricultural sector, fluorine-containing organic compounds exhibit significant insecticidal and fungicidal properties. In materials science, fluorine-containing methoxy compounds are widely used in the synthesis and modification of materials, such as batteries, coatings, and catalysts due to their excellent electrochemical performance and thermal stability. Consequently, the efficient introduction of fluorine-containing methoxy groups has become a focal point of research in organic chemistry. This review provides an overview of the preparation methods for monofluoromethoxy (OCH2F), difluoromethoxy (OCF2H), and trifluoromethoxy (OCF3) reagents, as well as the development of trifluoromethoxy reagents.
Wei Zheng , Fengxue Liu , Hongqiong Zhao , Ying Xu , Ning Chen , Yingjie Liu . Recent Progress on Methods for the Preparation of Mono/Di/Trifluoromethoxylation Reagents[J]. Chinese Journal of Organic Chemistry, 2024 , 44(11) : 3321 -3334 . DOI: 10.6023/cjoc202403011
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