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Chinese Journal of Organic Chemistry >

2024 , Vol. 44 >Issue 11: 3456 - 3466

DOI: https://doi.org/10.6023/cjoc202404019

ARTICLE

Pd-Catalyzed Reductive Cross-Coupling of Allylic Esters with Aryl Iodides Involving the Insertion of SO2

  • Xinwei Zhang ,
  • Shuizhen Lin ,
  • Xiaolei Huang
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  • Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, College of Chemistry and Materials Science, Zhejiang Normal University, Jinhua, Zhejiang 321004
*Corresponding author. E-mail:

Received date: 2024-04-13

  Revised date: 2024-05-13

  Online published: 2024-07-15

Supported by

National Natural Science Foundation of China(22101259); Zhejiang Provincial Natural Science Foundation(LQ22B020002)

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Abstract

A Pd-catalyzed electrophilic-electrophilic reductive cross-coupling of allylic esters with aryl iodides involving the insertion of SO2 has been reported. This reaction employs manganese powder as reductant, cheap and readily available sodium metabisulfite as SO2 substitute, and features good reactivity, high rselectivity and broad substrate scope.

Key words： palladium-catalysis; reductive cross-coupling; allylic ester; sodium metabisulfite; sulfur dioxide

Cite this article

Xinwei Zhang , Shuizhen Lin , Xiaolei Huang . Pd-Catalyzed Reductive Cross-Coupling of Allylic Esters with Aryl Iodides Involving the Insertion of SO2[J]. Chinese Journal of Organic Chemistry, 2024 , 44(11) : 3456 -3466 . DOI: 10.6023/cjoc202404019

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