Pd-Catalyzed Reductive Cross-Coupling of Allylic Esters with Aryl Iodides Involving the Insertion of SO2

doi:10.6023/cjoc202404019

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钯催化SO₂插入的烯丙基酯与芳基碘化物的还原偶联反应

张鑫伟, 林水侦, 黄晓雷^*

浙江师范大学化学与材料科学学院先进催化材料教育部重点实验室金华 321004

收稿日期:2024-04-13 修回日期:2024-05-13
基金资助:
浙江省自然科学基金(No. LQ22B020002)和国家自然科学基金(No. 22101259)资助项目.

Pd-Catalyzed Reductive Cross-Coupling of Allylic Esters with Aryl Iodides Involving the Insertion of SO₂

Zhang Xinwei, Lin Shuizhen, Huang Xiaolei^*

Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, College of Chemistry and Materials Science, Zhejiang Normal University, Jinhua, Zhejiang 321004

Received:2024-04-13 Revised:2024-05-13
Contact: * E-mail: huangxl@zjnu.edu.cn
Supported by:
Zhejiang Provincial Natural Science Foundation of China (No. LQ22B020002) and the National Natural Science Foundation of China (No. 22101259).

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Abstract

A Pd-catalyzed electrophilic-electrophilic reductive cross-coupling of allylic esters with aryl iodides involving the insertion of SO₂ has been reported. This reaction employs manganese powder as reductant, cheap and readily available sodium metabisulfite as SO₂ substitute, and features good reactivity, high rselectivity and broad substrate scope.

Key words: palladium-catalysis, reductive cross-coupling, allylic esters, sodium metabisulfite, sulfur dioxide

Cite this article

Zhang Xinwei, Lin Shuizhen, Huang Xiaolei. Pd-Catalyzed Reductive Cross-Coupling of Allylic Esters with Aryl Iodides Involving the Insertion of SO₂[J]. Chinese Journal of Organic Chemistry, doi: 10.6023/cjoc202404019.

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钯催化SO₂插入的烯丙基酯与芳基碘化物的还原偶联反应

Pd-Catalyzed Reductive Cross-Coupling of Allylic Esters with Aryl Iodides Involving the Insertion of SO₂

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钯催化SO2插入的烯丙基酯与芳基碘化物的还原偶联反应