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Chinese Journal of Organic Chemistry >

2025 , Vol. 45 >Issue 1: 319 - 324

DOI: https://doi.org/10.6023/cjoc202407011

ARTICLES

Synthesis and Electrochemical Study of Bipolar Molecules Containing Dihydrophenazine and Anthraquinone Moieties

  • Jianfa Li ,
  • An Duan ,
  • Xiaoyu Huang ,
  • Yongjun Li
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  • a Shanghai Institute of Organic Chemistry, Chinese Academy of Science, Shanghai 200032
    b School of Physical Science & Technology, ShanghaiTech University, Shanghai 201210
*E-mail: ;

Received date: 2024-07-04

  Revised date: 2024-07-12

  Online published: 2024-07-18

Supported by

National Natural Science Foundation of China(52273086); National Natural Science Foundation of China(U22A20131); Shanghai Scientific and Technological Innovation Project(22520711700)

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Abstract

Design and synthesis of electrochemical active molecules with high specific capacity attracted much research attention in the field of organic electrode materials for rechargeable betteries. Two bipolar molecules BPZ-AQ and 2BPZ-AQ which were composed of p-type dihydrophenazine and n-type anthraquinone moieties were synthesized via Buchwald-Hartwig coupling reaction. BPZ-AQ and 2BPZ-AQ could deliver high specific capacity of 230 and 223 mAh•g－1, respectively. Their bipolar-type property was investigated by absorption spectrum and cyclic voltammetry characterization, confirming the electrochemical activity of dihydrophenazine and anthraquinone moieties in the bipolar molecules. 2BPZ-AQ can present a high initial capacity of 210 mAh•g－1 at 1 C corresponding to 94% of its theoretical capacity, good capacity retention (60%) after 200 cycles, and excellent rate performance.

Key words： bipolar organics; anthraquinone; dihydrophenazine; organic cathode materials

Cite this article

Jianfa Li , An Duan , Xiaoyu Huang , Yongjun Li . Synthesis and Electrochemical Study of Bipolar Molecules Containing Dihydrophenazine and Anthraquinone Moieties[J]. Chinese Journal of Organic Chemistry, 2025 , 45(1) : 319 -324 . DOI: 10.6023/cjoc202407011

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