Synthesis and Electrochemical Study of Bipolar Molecules Containing Dihydrophenazine and Anthraquinone Moieties

doi:10.6023/cjoc202407011

Chinese Journal of Organic Chemistry

ARTICLE

含有二氢吩嗪和蒽醌的双极型分子的合成及其电化学性能研究

李建法^a,b, 段安^a, 黄晓宇^a,b,*, 李永军^a,*

^a中国科学院上海有机化学研究所上海 200032;
^b上海科技大学物质科学与技术学院上海 201210

收稿日期:2024-07-04 修回日期:2024-07-12
基金资助:
国家自然科学基金(52273086, U22A20131)和上海市国际合作项目(22520711700)资助项目.

Synthesis and Electrochemical Study of Bipolar Molecules Containing Dihydrophenazine and Anthraquinone Moieties

Jianfa Li^a,b, An Duan^a, Xiaoyu Huang^a,b,*, Yongjun Li^a,*

^aShanghai Institute of Organic Chemistry, CAS, Shanghai, 200032;
^bSchool of Physical Science & Technology, ShanghaiTech University, Shanghai 201210

Received:2024-07-04 Revised:2024-07-12
Contact: *E-mail: liyongjun78@sioc.ac.cn, xyhuang@mail.sioc.ac.cn
Supported by:
National Natural Science Foundation of China (52273086, U22A20131) and Shanghai Scientific and Technological Innovation Project (22520711700).

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Abstract

Design and synthesis of electrochemical active molecules with high specific capacity attracted much research attention in the field of organic electrode materials for rechargeable betteries. Here, two bipolar molecules (BPZ‒AQ and 2BPZ‒AQ) which were composed of p-type dihydrophenazine and n-type anthraquinone moieties were synthesized via Buchwald-Hartwig coupling reaction. BPZ‒AQ and 2BPZ‒AQ could deliver high specific capacity of 230 and 223 mAh g^-1, respectively. Their bipolar-type property was investigated by absorption spectrum and cyclic voltammetry characterization, confirming the electrochemical activity of dihydrophenazine and anthraquinone moieties in the bipolar molecules. 2BPZ‒AQ can present a high initial capacity of 210 mAh g^-1 at 1 C corresponding to 94% of its theoretical capacity, good capacity retention (60%) after 200 cycles, and excellent rate performance.

Key words: bipolar organics, anthraquinone, dihydrophenazine, organic cathode materials

Cite this article

Jianfa Li, An Duan, Xiaoyu Huang, Yongjun Li. Synthesis and Electrochemical Study of Bipolar Molecules Containing Dihydrophenazine and Anthraquinone Moieties[J]. Chinese Journal of Organic Chemistry, doi: 10.6023/cjoc202407011.

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含有二氢吩嗪和蒽醌的双极型分子的合成及其电化学性能研究

Synthesis and Electrochemical Study of Bipolar Molecules Containing Dihydrophenazine and Anthraquinone Moieties

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