REWIEW

Advances in Organouranium Complexes Containing Redox-Active Non-innocent Ligands

  • 曹小英 ,
  • 衡义 ,
  • 王东伟 ,
  • 杨丕堃 ,
  • 侯国华 ,
  • 自国甫
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  • College of Chemistry, Beijing Normal University, Beijing 100875

Received date: 2025-10-16

  Revised date: 2025-11-17

  Online published: 2025-12-30

Supported by

National Natural Science Foundation of China (Nos. 22571018, 22271017, 22571021).

Abstract

Over the past two decades, the low-valent organoactinide complexes containing redox-active non-innocent ligands have become one of the most promising research frontiers in organometallic chemistry due to their fundamental importance and their extensive applications in organic synthesis, chemical engineering and catalytic processes. Among these, low-valent organouranium complexes have received widespread attention because of their unique structural properties and their potential applications in group transfer and catalysis. Currently, low-valent organouranium complexes containing redox-active non-innocent ligands, in particularly those derived from 2,2′-bipyridine, 1,4-diazabutadienes, pyridine diimines and arenes have been regarded as one of the most remarkable research hotspots in organometallic chemistry. This review summarizes the advances in the preparation of such complexes and their reactivity in small molecule activation.

Cite this article

曹小英 , 衡义 , 王东伟 , 杨丕堃 , 侯国华 , 自国甫 . Advances in Organouranium Complexes Containing Redox-Active Non-innocent Ligands[J]. Chinese Journal of Organic Chemistry, 0 : 123012 -123012 . DOI: 10.6023/cjoc202510012

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