Advances in Organouranium Complexes Containing Redox-Active Non-innocent Ligands

doi:10.6023/cjoc202510012

Abstract

Over the past two decades, the low-valent organoactinide complexes containing redox-active non-innocent ligands have become one of the most promising research frontiers in organometallic chemistry due to their fundamental importance and their extensive applications in organic synthesis, chemical engineering and catalytic processes. Among these, low-valent organouranium complexes have received widespread attention because of their unique structural properties and their potential applications in group transfer and catalysis. Currently, low-valent organouranium complexes containing redox-active non-innocent ligands, in particularly those derived from 2,2′-bipyridine, 1,4-diazabutadienes, pyridine diimines and arenes have been regarded as one of the most remarkable research hotspots in organometallic chemistry. This review summarizes the advances in the preparation of such complexes and their reactivity in small molecule activation.

Key words: organouranium, redox-active non-innocent ligand, preparation, reactivity

Cite this article

Cao, Xiaoying, Heng, Yi, Wang, Dongwei, Yang, Pikun, Hou, Guohua, Zi, Guofu^*/sup>. Advances in Organouranium Complexes Containing Redox-Active Non-innocent Ligands[J]. Chinese Journal of Organic Chemistry, doi: 10.6023/cjoc202510012.

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氧化还原活性配体衍生的有机铀化合物研究进展