网状框架中的机械互锁结构

doi:10.6023/A20050147

化学学报 ›› 2020, Vol. 78 ›› Issue (8): 746-757.DOI: 10.6023/A20050147 上一篇下一篇

所属专题：多孔材料：金属有机框架(MOF)；多孔材料：共价有机框架(COF)

综述

网状框架中的机械互锁结构

王友付, 刘航海, 朱新远

上海交通大学化学化工学院变革性分子前沿科学中心上海 200240

投稿日期:2020-05-07 发布日期:2020-06-16
通讯作者: 王友付 E-mail:wyfown@sjtu.edu.cn
作者简介:王友付,上海交通大学化学化工学院助理研究员.分别于2011和2016年获得华东理工大学学士和博士学位,博士期间通过国家公派在美国芝加哥大学进行两年的联合培养.随后入选博士后创新人才支持计划进入上海交通大学从事博士后研究,合作导师为朱新远教授.2018年底加入上海交通大学,研究工作主要围绕低维有序纳米材料的设计构筑和聚合物模板化的纳米制备.
朱新远,上海交通大学教授,博士生导师.分别于1994和1997年获东华大学学士和硕士学位;2001年获上海交通大学博士学位,师从颜德岳院士;2003年至2005年在法国斯特拉斯堡大学从事博士后研究,合作导师为Volker Shaedler.当前的研究兴趣为功能聚合物的可控制备及其生物医药应用.
基金资助:
项目受国家自然科学基金（No.21805130）和上海市科委（Nos.18JC1410800，17ZR1441300）资助.

Mechanically Interlocked Structures within Reticular Frameworks

Wang Youfu, Liu Hanghai, Zhu Xinyuan

School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, Shanghai Jiao Tong University, Shanghai 200240

Received:2020-05-07 Published:2020-06-16
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21805130) and the Science and Technology Commission of Shanghai Municipality (Nos. 18JC1410800, 17ZR1441300).

文章分享

摘要/Abstract

网状框架具有结晶而延伸的多孔结构，不仅能将多种构筑模块按预期的方式有序组织形成介观材料，也因其可调控的精确结构成为研究基础科学问题的良好平台.机械互锁结构是利用分子间的机械作用将多种分子结合起来以协同实现复杂功能的分子集合体.将网状框架与机械互锁结构结合不仅能实现机械互锁结构的高维度有序组装以协同实现更复杂的分子机器的功能，也有望对更有应用前景的固相中机械互锁结构间的相互作用和微观机理有更深入的认识.本综述介绍了网状框架与机械互锁结构结合的研究领域的重要进展，第一部分在分别简要介绍网状框架和机械互锁结构的基础上阐述了两个领域结合的意义和策略；第二部分主要介绍了机械互锁结构作为构筑模块参与网状框架构建的系统性和代表性工作，包括含轮烷和索烃的构筑模块；第三部分则是介绍由机械互锁作用为主要相互作用构筑的网状框架，包括弹性编织框架和机械互锁框架，最后对全文进行总结并对该领域的后续发展方向予以探讨.

关键词: 金属有机框架, 共价有机框架, 机械互锁结构, 弹性编织框架, 机械互锁框架

The reticular frameworks have crystalline and extended porous structures, which can not only orderly organize a variety of building blocks to form mesoscopic materials in a programmable way, but also perform an excellent platform for basic scientific research because of the regulatable and precise structures. The representative systems of reticular frameworks are metal organic frameworks (MOFs) and covalent organic frameworks (COFs). Mechanically interlocked structures are molecular aggregations interacted through mechanical bond to realize complex functions. The combination of reticular frameworks and mechanically interlocked structures can promote the basic research of the microscopic interlocked behaviors in solid states; and also organize the interlocked structures in a regular way to achieve more complex functions. The mechanically interlocked structures can be introduced into reticular frameworks in two strategies, using mechanically interlocked structures as building blocks participating in the construction of reticular frameworks; and forming woven or interlocked frameworks with whole interlocked skeleton from unlocked precursors. This review summarizes the important progresses in the emerging research field combining the reticular frameworks and mechanically interlocked structures. In the first section, after the brief introduction of reticular frameworks and mechanically interlocked structures respectively, the significances and strategies of the combination of the above two fields is described. In the second section, we reveal the systematic and representative research of mechanically interlocked structure as a part of building blocks participating in the construction of reticular frameworks, including rotaxane, shuttle and catenate. The mechanical motions of rotaxanes and shuttle within MOFs are intensively studied. The representative methods and structures of introducing rotaxane or catenate into reticular frameworks are presented. In the third section, we exhibit the reticular frameworks constructed through mechanical bond as the main interaction within the whole skeleton from unlocked precursors, including resilient woven frameworks and mechanically interlocked frameworks. The typical woven or interlocked frameworks are mostly templated from special metal complexes and showing reversible transition between crystal and non-crystal maintaining the whole interlocked skeleton. Finally, we summarize the whole paper and discuss the future development in this crossing field, such as the applications of these combined systems should be expanded and the mechanically interlocked frameworks constructed through interlocking discrete molecular rings are expected due to the potential excellent elastic properties.

Key words: metal organic frameworks, covalent organic frameworks, mechanically interlocked structures, resilient woven frameworks, mechanically interlocked frameworks

引用此文

王友付, 刘航海, 朱新远. 网状框架中的机械互锁结构[J]. 化学学报, 2020, 78(8): 746-757.

Wang Youfu, Liu Hanghai, Zhu Xinyuan. Mechanically Interlocked Structures within Reticular Frameworks[J]. Acta Chimica Sinica, 2020, 78(8): 746-757.

导出引用 EndNote|Reference Manager|ProCite|BibTeX|RefWorks

分享此文

参考文献

[1] (a) Rungtaweevoranit, B.; Diercks, C. S.; Kalmutzki, M. J.; Yaghi, Omar M. Faraday Discuss. 2017, 201, 9. (b) Yaghi, O. M. Mol. Front. J. 2019, 3, 66.
[2] (a) Li, B.; Chrzanowski, M.; Zhang, Y.; Ma, S. Coord. Chem. Rev. 2016, 307, 106. (b) Safaei, M.; Foroughi, M. M.; Ebrahimpoor, N.; Jahani, S.; Omidi, A.; Khatami, M. Trac-Trends Anal. Chem. 2019, 118, 401. (c) Liu, Z.; Li, W.; Liu, H.; Zhuang, X.; Li, S. Acta Chim. Sinica 2019, 77, 323. (刘治鲁, 李炜, 刘昊, 庄旭东, 李松, 化学学报, 2019, 77, 323.) (d) Zeng, J.; Wang, X.; Zhang, X.; Zhuo, R. Acta Chim. Sinica 2019, 77, 1156. (曾锦跃, 王小双, 张先正, 卓仁禧, 化学学报, 2019, 77, 1156.) (e) Chen, Z.; Liu, J.; Cui, H.; Zhang, L.; Su, C. Acta Chim. Sinica 2019, 77, 242. (陈之尧, 刘捷威, 崔浩, 张利, 苏成勇, 化学学报, 2019, 77, 242.) (f) Zhang, X.; Wang, X.; Fan, W.; Sun, D. Chin. J. Chem. 2020, 38, 509.
[3] (a) Huang, N.; Wang, P.; Jiang, D. Nat. Rev. Mater. 2016, 1, 16068. (b) Lohse, M. S.; Bein, T. Adv. Funct. Mater. 2018, 28, 1705553. (c) Pang, C.; Luo, S.; Hao, Z.; Gao, J.; Huang, Z.; Yu, J.; Yu, S.; Wang, C. Chin. J. Org. Chem. 2018, 38, 2606. (庞楚明, 罗时荷, 郝志峰, 高健, 黄召昊, 余家海, 余思敏, 汪朝阳, 有机化学, 2018, 38, 2606.)
[4] (a) Denis, M.; Goldup, S. M. Nat. Rev. Chem. 2017, 1, 0061. (b) Mena-Hernando, S.; Pérez, E. M. Chem. Soc. Rev. 2019, 48, 5016.
[5] Stoddart, J. F. Angew. Chem. Int. Ed. 2017, 56, 11094.
[6] Leigh, D. A.; Pritchard, R. G.; Stephens, A. J. Nat. Chem. 2014, 6, 978.
[7] (a) Beves, J. E.; Blight, B. A.; Campbell, C. J.; Leigh, D. A.; McBurney, R. T. Angew. Chem. Int. Ed. 2011, 50, 9260. (b) Forgan, R. S.; Sauvage, J.-P.; Stoddart, J. F. Chem. Rev. 2011, 111, 5434.
[8] (a) Niu, Z.; Gibson, H. W. Chem. Rev. 2009, 109, 6024. (b) Wu, Q.; Rauscher, P. M.; Lang, X.; Wojtecki, R. J.; de Pablo, J. J.; Hore, M. J. A.; Rowan, S. J. Science 2017, 358, 1434.
[9] (a) Jiang, X.; Duan, H.-B.; Khan, S. I.; Garcia-Garibay, M. A. ACS Cent. Sci. 2016, 2, 608. (b) Vogelsberg, C. S.; Uribe-Romo, F. J.; Lipton, A. S.; Yang, S.; Houk, K. N.; Brown, S.; Garcia-Garibay, M. A. Proc. Natl. Acad. Sci. U. S. A. 2017, 114, 13613. (c) Gonzalez-Nelson, A.; Coudert, F.-X.; van der Veen, M. A. Nanomaterials 2019, 9, 330.
[10] Danowski, W.; van Leeuwen, T.; Abdolahzadeh, S.; Roke, D.; Browne, W. R.; Wezenberg, S. J.; Feringa, B. L. Nat. Nanotechnol. 2019, 14, 488.
[11] Martinez-Bulit, P.; Stirk, A. J.; Loeb, S. J. Trends in Chemistry 2019, 1, 588.
[12] (a) Hoffart, D. J.; Loeb, S. J. Angew. Chem. Int. Ed. 2005, 44, 901. (b) Loeb, S. J. Chem. Commun. 2005, 1511. (c) Vukotic, V. N.; Loeb, S. J. Chem. Soc. Rev. 2012, 41, 5896. (d) Yang, J.; Ma, J.-F.; Batten, S. R. Chem. Commun. 2012, 48, 7899.
[13] Vukotic, V. N.; Harris, K. J.; Zhu, K.; Schurko, R. W.; Loeb, S. J. Nat. Chem. 2012, 4, 456.
[14] Vukotic, V. N.; O’Keefe, C. A.; Zhu, K.; Harris, K. J.; To, C.; Schurko, R. W.; Loeb, S. J. J. Am. Chem. Soc. 2015, 137, 9643.
[15] Zhu, K.; Vukotic, V. N.; O’Keefe, C. A.; Schurko, R. W.; Loeb, S. J. J. Am. Chem. Soc. 2014, 136, 7403.
[16] Farahani, N.; Zhu, K.; O'Keefe, C. A.; Schurko, R. W.; Loeb, S. J. ChemPlusChem 2016, 81, 836.
[17] Zhu, K.; O'Keefe, C. A.; Vukotic, V. N.; Schurko, R. W.; Loeb, S. J. Nat. Chem. 2015, 7, 514.
[18] Jonathan, C.; David, R.; Cory M., S. ChemRxiv 2019, doi.org/ 10.26434/chemrxiv.9942095.v1
[19] Coskun, A.; Hmadeh, M.; Barin, G.; Gándara, F.; Li, Q.; Choi, E.; Strutt, N. L.; Cordes, D. B.; Slawin, A. M. Z.; Stoddart, J. F.; Sauvage, J. P.; Yaghi, O. M. Angew. Chem. Int. Ed. 2012, 51, 2160.
[20] Deria, P.; Mondloch, J. E.; Karagiaridi, O.; Bury, W.; Hupp, J. T.; Farha, O. K. Chem. Soc. Rev. 2014, 43, 5896.
[21] McGonigal, P. R.; Deria, P.; Hod, I.; Moghadam, P. Z.; Avestro, A.-J.; Horwitz, N. E.; Gibbs-Hall, I. C.; Blackburn, A. K.; Chen, D.; Botros, Y. Y.; Wasielewski, M. R.; Snurr, R. Q.; Hupp, J. T.; Farha, O. K.; Stoddart, J. F. Proc. Natl. Acad. Sci. U. S. A. 2015, 112, 11161.
[22] Wang, T. C.; Vermeulen, N. A.; Kim, I. S.; Martinson, A. B. F.; Stoddart, J. F.; Hupp, J. T.; Farha, O. K. Nat. Protoc. 2016, 11, 149.
[23] (a) Li, Q.; Zhang, W.; Miljanić, O. Š.; Sue, C.-H.; Zhao, Y.-L.; Liu, L.; Knobler, C. B.; Stoddart, J. F.; Yaghi, O. M. Science 2009, 325, 855. (b) Zhang, H.; Zou, R.; Zhao, Y. Coord. Chem. Rev. 2015, 292, 74.
[24] Sue, A. C.-H.; Mannige, R. V.; Deng, H.; Cao, D.; Wang, C.; Gándara, F.; Stoddart, J. F.; Whitelam, S.; Yaghi, O. M. Proc. Natl. Acad. Sci. U. S. A. 2015, 112, 5591.
[25] Li, Q.; Zhang, W.; Miljanić, O. Š.; Knobler, C. B.; Stoddart, J. F.; Yaghi, O. M. Chem. Commun. 2010, 46, 380.
[26] Li, Q.; Sue, C.-H.; Basu, S.; Shveyd, A. K.; Zhang, W.; Barin, G.; Fang, L.; Sarjeant, A. A.; Stoddart, J. F.; Yaghi, O. M. Angew. Chem. Int. Ed. 2010, 49, 6751.
[27] Cao, D.; Juríček, M.; Brown, Z. J.; Sue, A. C.-H.; Liu, Z.; Lei, J.; Blackburn, A. K.; Grunder, S.; Sarjeant, A. A.; Coskun, A.; Wang, C.; Farha, O. K.; Hupp, J. T.; Stoddart, J. F. Chem.-Eur. J. 2013, 19, 8457.
[28] Lewis, J. E. M. Org. Biomol. Chem. 2019, 17, 2442.
[29] Chen, Q.; Sun, J.; Li, P.; Hod, I.; Moghadam, P. Z.; Kean, Z. S.; Snurr, R. Q.; Hupp, J. T.; Farha, O. K.; Stoddart, J. F. J. Am. Chem. Soc. 2016, 138, 14242.
[30] (a) Wang, Z.; Błaszczyk, A.; Fuhr, O.; Heissler, S.; Wöll, C.; Mayor, M. Nat. Commun. 2017, 8, 14442. (b) Champsaur, A. M.; Mézière, C.; Allain, M.; Paley, D. W.; Steigerwald, M. L.; Nuckolls, C.; Batail, P. J. Am. Chem. Soc. 2017, 139, 11718. (c) Lewandowska, U.; Zajaczkowski, W.; Corra, S.; Tanabe, J.; Borrmann, R.; Benetti, E. M.; Stappert, S.; Watanabe, K.; Ochs, N. A. K.; Schaeublin, R.; Li, C.; Yashima, E.; Pisula, W.; Mullen, K.; Wennemers, H. Nat. Chem. 2017, 9, 1068.
[31] Liu, Y.; Yaghi, O. M. Bull. Jpn. Soc. Coord. Chem. 2018, 71, 12.
[32] Liu, Y.; Ma, Y.; Zhao, Y.; Sun, X.; Gándara, F.; Furukawa, H.; Liu, Z.; Zhu, H.; Zhu, C.; Suenaga, K.; Oleynikov, P.; Alshammari, A. S.; Zhang, X.; Terasaki, O.; Yaghi, O. M. Science 2016, 351, 365.
[33] Liu, Y.; Ma, Y.; Yang, J.; Diercks, C. S.; Tamura, N.; Jin, F.; Yaghi, O. M. J. Am. Chem. Soc. 2018, 140, 16015.
[34] Xu, H.-S.; Luo, Y.; Li, X.; See, P. Z.; Chen, Z.; Ma, T.; Liang, L.; Leng, K.; Abdelwahab, I.; Wang, L.; Li, R. L.; Shi, X. Y.; Zhou, Y.; Lu, X. F.; Zhao, X. X.; Liu, C. B.; Sun, J. L.; Loh, K. P. Nat. Commun. 2020, 11, 1434.
[35] Xu, H.-S.; Luo, Y.; See, P. Z.; Li, X.; Chen, Z.; Zhou, Y.; Zhao, X.; Leng, K.; Park, I.-H.; Li, R.; Liu, C.; Chen, F.; Xi, S.; Sun, J.; Loh, K. P. Angew. Chem. Int. Ed. 2020, 59, 11527.
[36] Zhao, Y.; Guo, L.; Gándara, F.; Ma, Y.; Liu, Z.; Zhu, C.; Lyu, H.; Trickett, C. A.; Kapustin, E. A.; Terasaki, O.; Yaghi, O. M. J. Am. Chem. Soc. 2017, 139, 13166.
[37] (a) Tian, J.; Chen, L.; Zhang, D.-W.; Liu, Y.; Li, Z.-T. Chem. Commun. 2016, 52, 6351. (b) Zhang, K.-D.; Tian, J.; Hanifi, D.; Zhang, Y.; Sue, A. C.-H.; Zhou, T.-Y.; Zhang, L.; Zhao, X.; Liu, Y.; Li, Z.-T. J. Am. Chem. Soc. 2013, 135, 17913. (c) Xu, S.-Q.; Zhang, X.; Nie, C.-B.; Pang, Z.-F.; Xu, X.-N.; Zhao, X. Chem. Commun. 2015, 51, 16417. (d) Li, Y.; Dong, Y.; Miao, X.; Ren, Y.; Zhang, B.; Wang, P.; Yu, Y.; Li, B.; Isaacs, L.; Cao, L. Angew. Chem. Int. Ed. 2018, 57, 729. (e) Lee, H.-J.; Kim, H.-J.; Lee, E.-C.; Kim, J.; Park, S. Y. Chem.-Asian J. 2018, 13, 390.
[38] Tian, J.; Xu, Z.-Y.; Zhang, D.-W.; Wang, H.; Xie, S.-H.; Xu, D.-W.; Ren, Y.-H.; Wang, H.; Liu, Y.; Li, Z.-T. Nat. Commun. 2016, 7, 11580.
[39] Liu, Y.; Diercks, C. S.; Ma, Y.; Lyu, H.; Zhu, C.; Alshmimri, S. A.; Alshihri, S.; Yaghi, O. M. J. Am. Chem. Soc. 2019, 141, 677.
[40] Thorp-Greenwood, F. L.; Kulak, A. N.; Hardie, M. J. Nat. Chem. 2015, 7, 526.
[41] Lewis, J. E. M.; Beer, P. D.; Loeb, S. J.; Goldup, S. M. Chem. Soc. Rev. 2017, 46, 2577.
[42] Liu, Y.; O'Keeffe, M.; Treacy, M. M. J.; Yaghi, O. M. Chem. Soc. Rev. 2018, 47, 4642.

网状框架中的机械互锁结构

Mechanically Interlocked Structures within Reticular Frameworks

PDF

可视化

摘要/Abstract

引用此文

分享此文

参考文献

相关文章 15

编辑推荐

相关统计

本文评价

[1]	刘洋, 高丰琴, 马占营, 张引莉, 李午戊, 侯磊, 张小娟, 王尧宇. 一例钴基金属有机框架化合物活化过氧单硫酸盐高效降解水中亚甲基蓝研究[J]. 化学学报, 2024, 82(2): 152-159.
[2]	魏颖, 王家成, 李玥, 汪涛, 马述威, 解令海. 碳碳键链接的二维共价有机框架研究进展[J]. 化学学报, 2024, 82(1): 75-102.
[3]	刘建川, 李翠艳, 刘耀祖, 王钰杰, 方千荣. 高稳定二维联咔唑sp²碳共轭共价有机框架材料用于高效电催化氧还原^★[J]. 化学学报, 2023, 81(8): 884-890.
[4]	杨蓉婕, 周璘, 苏彬. 基于共价有机框架修饰电极的维生素A和C的选择性检测^★[J]. 化学学报, 2023, 81(8): 920-927.
[5]	孙博, 琚雯雯, 王涛, 孙晓军, 赵婷, 卢晓梅, 陆峰, 范曲立. 高分散共轭聚合物-金属有机框架纳米立方体的制备及抗肿瘤应用[J]. 化学学报, 2023, 81(7): 757-762.
[6]	何明慧, 叶子秋, 林桂庆, 尹晟, 黄心翊, 周旭, 尹颖, 桂波, 汪成. 卟啉基共价有机框架的光催化研究进展^★[J]. 化学学报, 2023, 81(7): 784-792.
[7]	齐学平, 王飞, 张健. 后合成法构筑钛基金属有机框架及其应用[J]. 化学学报, 2023, 81(5): 548-558.
[8]	殷政, 赵英博, 曾明华. 动态化学与材料和非晶物理新关联——金属有机框架玻璃的挑战、进展与新机遇[J]. 化学学报, 2023, 81(3): 246-252.
[9]	陈俊畅, 张明星, 王殳凹. 晶态多孔材料合成方法的研究进展[J]. 化学学报, 2023, 81(2): 146-157.
[10]	程敏, 王诗慧, 罗磊, 周利, 毕可鑫, 戴一阳, 吉旭. 面向乙烷/乙烯分离的金属有机框架膜的大规模计算筛选[J]. 化学学报, 2022, 80(9): 1277-1288.
[11]	闫绍兵, 焦龙, 何传新, 江海龙. ZIF-67/石墨烯复合物衍生的氮掺杂碳限域Co纳米颗粒用于高效电催化氧还原[J]. 化学学报, 2022, 80(8): 1084-1090.
[12]	闫续, 屈贺幂, 常烨, 段学欣. 金属有机框架在气体预富集、预分离及检测中的应用[J]. 化学学报, 2022, 80(8): 1183-1202.
[13]	何家伟, 焦柳, 程雪怡, 陈光海, 吴强, 王喜章, 杨立军, 胡征. 金属有机框架衍生的空心碳纳米笼的结构调控与锂硫电池性能研究[J]. 化学学报, 2022, 80(7): 896-902.
[14]	谢晨帆, 徐玉平, 高明亮, 徐忠宁, 江海龙. MOF基Pd单位点催化CO酯化制碳酸二甲酯[J]. 化学学报, 2022, 80(7): 867-873.
[15]	曹琳安, 魏敏. 电子导电金属有机框架薄膜的研究进展[J]. 化学学报, 2022, 80(7): 1042-1056.